178265-54-8

Basic information

• Product Name: 3-(4-Amino-phenyl)-1,5-di-pyridin-2-yl-pentane-1,5-dione
• Synonyms: 3-(4-Amino-phenyl)-1,5-di-pyridin-2-yl-pentane-1,5-dione
• CAS NO: 178265-54-8
• Molecular Weight: 345.401
• Mol File: 178265-54-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-(4-Amino-phenyl)-1,5-di-pyridin-2-yl-pentane-1,5-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-Amino-phenyl)-1,5-di-pyridin-2-yl-pentane-1,5-dione(178265-54-8)
• EPA Substance Registry System: 3-(4-Amino-phenyl)-1,5-di-pyridin-2-yl-pentane-1,5-dione(178265-54-8)

Safety Data

• Hazardous Substances Data: 178265-54-8(Hazardous Substances Data)

Upstream product

• 1122-62-9 2-acetylpyridine 
• 556-18-3 4-aminobenzaldehyde 

Downstream Products

• 196202-50-3 2,5-Bis-(4-[2,2';6',2'']terpyridin-4'-yl-phenylcarbamoyl)-terephthalic acid 
• 196202-14-9 4'-[4-(5-ethoxy-1,4-benzoquinon-2-ylamino)phenyl]-2,2':6',2''-terpyridine 
• 196202-13-8 4'-(benzamidophenyl)-2,2':6',2''-terpyridine 
• 178265-51-5 N,N'-bis[4-(2,2':6',2''-terpyridin-4'-yl)phenyl]pyromellitimide 
• 178265-52-6 N,N'-bis[4-(2,2':6',2''-terpyridin-4'-yl)phenyl]terephthalamide 
• 178265-53-7 N,N'-bis[4-(2,2':6',2''-terpyridin-4'-yl)phenyl]adipamide 
• 178265-65-1 4′-(4-amino-phenyl)-2,2′:6′,2′′-terpyridine 

Relevant articles and documents

Bis[4′-(4-anilino)-2,2′:6′,2″-terpyridine] transition-metal complexes: Electrochemically active monomers with a range of magnetic and optical properties for assembly of metallo oligomers and macromolecules

The new ligand 4′-(4-anilino)-2,2′:6′,2″-terpyridine (L1) and a range of its transition-metal complexes have been prepared. The crystal and molecular structures of L1 and [CuL12[PF6]2 have been determined. Model reactions show that L1 and its transition-metal complexes can be functionalised with suitable organic reagents: reactions with aromatic dianhydrides give imide derivatives, reactions with acid chlorides afford amide derivatives and benzoquinone reacts with L1 to give a quinonylanilinoterpyridine ligand, complexes of which are described, but not with the complexes of L1. The use of L1 and its complexes in building up multicomponent architectures has been tested. Metallo-dimers and co-ordination polymers linked by new binucleating bis(terpyridyl) ligands have been prepared by two routes: (a) first coupling two L1 with difunctional organic reagents and then treating the new binucleating ligands with a metal source, or (b) preforming monomeric complexes of L1 and treating these with the same difunctional organic reagents. Analytical, spectroscopic and electrochemical data are given for all complexes; the chromophoric, magnetic and electrochemical properties of the complexes vary with transition metal and terpyridyl ligand substituent.