178265-65-1

Usage

Uses

Used in Coordination Chemistry:
4'-(4-Aminophenyl)-2,2':6',2''-terpyridine is used as a ligand in coordination chemistry for its capacity to bind with metal ions, forming stable complexes. These complexes are of interest due to their potential applications in various areas, including catalysis, luminescent materials, and molecular sensing.
Used in Materials Science:
In the field of materials science, 4'-(4-Aminophenyl)-2,2':6',2''-terpyridine is utilized for the development of advanced materials. Its metal complexes have been studied for their possible use in creating materials with unique optical, electronic, and catalytic properties.
Used in Supramolecular Chemistry:
4'-(4-Aminophenyl)-2,2':6',2''-terpyridine is also used as a building block in supramolecular chemistry. Its ability to self-assemble into complex structures allows for the creation of intricate molecular architectures with potential applications in molecular recognition and self-healing materials.
Used in Catalysis:
4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE serves as a catalyst or a catalyst precursor in various chemical reactions. Its metal complexes can enhance the efficiency and selectivity of catalytic processes, making it valuable in industrial applications.
Used in Luminescent Materials:
4'-(4-Aminophenyl)-2,2':6',2''-terpyridine and its metal complexes are used in the development of luminescent materials. These materials can be applied in optoelectronics, such as light-emitting diodes (LEDs) and solar cells, due to their light-emitting properties.
Used in Molecular Sensing:
4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE is utilized in molecular sensing applications, where its metal complexes can selectively bind and detect specific molecules or ions. This makes it useful in environmental monitoring, medical diagnostics, and other sensing technologies.

Upstream product

• 129077-51-6 4’-(4-nitrophenyl)-2,2’,6’,2’’-terpyridine 
• 128143-89-5 4'-Chloro-2,2':6',2''-terpyridine 
• 214360-73-3 4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)aniline 
• 26482-00-8 1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide 
• 18451-69-9 (2E)-3-(4-nitrophenyl)-1-(pyridin-2-yl)prop-2-en-1-one 
• 555-16-8 4-nitrobenzaldehdye 
• 1122-62-9 2-acetylpyridine 
• 556-18-3 4-aminobenzaldehyde 
• 16232-01-2 (2E)-3-(4-bromophenyl)-1-(pyridin-2-yl)prop-2-en-1-one 
• 1122-91-4 4-bromo-benzaldehyde 
• 122-85-0 para-acetamidobenzaldehyde 
• 89972-76-9 4'-(4-bromo-phenyl)-[2,2';6',2'']terpyridine 
• 178265-54-8 3-(4-Amino-phenyl)-1,5-di-pyridin-2-yl-pentane-1,5-dione 

Downstream Products

• 178265-51-5 N,N'-bis[4-(2,2':6',2''-terpyridin-4'-yl)phenyl]pyromellitimide 
• 178265-53-7 N,N'-bis[4-(2,2':6',2''-terpyridin-4'-yl)phenyl]adipamide 
• 1115638-57-7 C₂₈H₁₉N₅O₃ 
• 42386-81-2 bis(2,2':6',2''-terpyridine)ruthenium(III)⁽³⁺⁾ 
• 178265-55-9 [Ru(C₁₅H₁₁N₃)(C₂₁H₁₆N₄)]⁽²⁺⁾ 
• 1073314-51-8 4'-(N-(4-(2,4-dioxopentan-3-yl)phenyl)benamide)2,2':6',2''-terpyridine 

Relevant academic research and scientific papers

Rapid self-healing and anion selectivity in metallosupramolecular gels assisted by fluorine-fluorine interactions

Simple ML2 [M = Fe(II), Co(II), Ni(II)] complexes obtained from a perfluoroalkylamide derivative of 4-aminophenyl-2,2′,6,2′-terpyridine spontaneously, yet anion selectively, self-assemble into gels, which manifest an unprecedented rapid gel strength recovery, viz. self-healing, and thermal rearrangement in aqueous dimethyl sulfoxide. The key factor for gelation and rheological properties emerges from the fluorine-fluorine interactions between the perfluorinated chains, as the corresponding hydrocarbon derivative did not form metallogels. The perfluoro-terpyridine ligand alone formed single crystals, while its Fe(II), Co(II) or Ni(II) complexes underwent rapid gelation leading to highly entangled fibrillar networks visualized by electron microscopy. The thermodynamic parameters of gelation based on variable temperature NMR 1H and 19F resonances showed that gelation was enthalpically favourable and entropically disfavourable. The step strain rheological experiments revealed that the gels undergo rapid self-healing and the morphological features, thermal stability and mechanical properties were found to depend on the nature of the metal ion.

A luminescent ph-responsive ternary europium(Iii) complex of β-diketonates and terpyridine derivatives as sensitizing antennae – photophysical aspects, anion sensing, and biological interactions

The highly luminescent stable Eu3+ complex [Eu(tta)3(naptpy)] [1, tta = 2-thenoyltrifluoroacetone, naptpy = 2-{4-[(2,2′:6′,2′′-terpyridin)-4′-yl]phenyl}-6-bromo-1H benzo-[de]isoquinoline-1,3(2H)-dione] was designed as a pH-responsive anion-sens

Photophysical properties of osmium(II) complexes with the novel 4'-p-phenylterpyridine-triarylpyridinium ligand

A new family of electron acceptor ligands complexed with osmium(II) and associated with appropriate electron donor subunits within heteroleptic compounds, results in multicomponent assemblies of potential interest for both synthetic chemistry and supramol

Transition metal ion induced hydrogelation by amino-terpyridine ligands

Hydrogelation behavior of two amino-terpyridine ligands in the presence of divalent metal ions in water was studied in detail. The effect of ligand structure and different counter anions on the gel morphologies was also explored. This journal is

Fluorescent supramolecular polymers: Metal directed self-assembly of perylene bisimide building blocks

Complezation properties of 2,2′:6′,2″-terpyridine (tpy) have been studied with, a series of first row transition metal ions by UV-vis, 1H NMR, and isothermal titration calorimetry, and AH values for the tpy complexation processes have been dete

Palladium supported terpyridine modified magnetic nanoparticles as an efficient catalyst for carbon-carbon bond formation

In this paper, a novel catalyst is designed, synthesized and characterized based on the functionalization of magnetic iron oxide nanoparticles by terpyridine as a ligand for the immobilization of palladium. The catalyst is fully characterized by several c

Luminescent lanthanide(III) complexes of DTPA-bis(amido-phenyl-terpyridine) for bioimaging and phototherapeutic applications

We report here a series of coordinatively-saturated and thermodynamically stable luminescent [Ln(dtntp)(H2O)] [Ln(III) = Eu (1), Tb (2), Gd (3), Sm (4) and Dy (5)] complexes using an aminophenyl-terpyridine appended-DTPA (dtntp) chelating ligand as cell imaging and photocytotoxic agents. The N,N″-bisamide derivative of H5DTPA named as dtntp is based on 4′-(4-aminophenyl)-2,2′:6′,2″-terpyridine conjugated to diethylenetriamine-N,N′,N″-pentaacetic acid. The structure, physicochemical properties, detailed photophysical aspects, interaction with DNA and serum proteins, and photocytotoxicity were studied. The intrinsic luminescence of Eu(III) and Tb(III) complexes due to f → f transitions used to evaluate their cellular uptake and distribution in cancer cells. The solid-state structure of [Eu(dtntp)(DMF)] (1·DMF) shows a discrete mononuclear molecule with nine-coordinated {EuN3O6} distorted tricapped-trigonal prism (TTP) coordination geometry around the Eu(III). The {EuN3O6} core results from three nitrogen atoms and three carboxylate oxygen atoms, and two carbonyl oxygen atoms of the amide groups of dtntp ligand. The ninth coordination site is occupied by an oxygen atom of DMF as a solvent from crystallization. The designed probes have two aromatic pendant phenyl-terpyridine (Ph-tpy) moieties as photo-sensitizing antennae to impart the desirable optical properties for cellular imaging and photocytotoxicity. The photostability, coordinative saturation, and energetically rightly poised triplet states of dtntp ligand allow the efficient energy transfer (ET) from Ph-tpy to the emissive excited states of the Eu(III)/Tb(III), makes them luminescent cellular imaging probes. The Ln(III) complexes show significant binding tendency to DNA (K ~ 104 M?1), and serum proteins (BSA and HSA) (K ~ 105 M?1). The luminescent Eu(III) (1) and Tb(III) (2) complexes were utilized for cellular internalization and cytotoxicity studies due to their optimal photophysical properties. The cellular uptake studies using fluorescence imaging displayed intracellular (cytosolic and nuclear) localization in cancer cells. The complexes 1 and 2 displayed significant photocytotoxicity in HeLa cells. These results offer a modular design strategy with further scope to utilize appended N,N,N-donor tpy moiety for developing light-responsive luminescent Ln(III) bioprobes for theranostic applications.

Aggregation induced emission (AIE) active 4-amino-1,8-naphthalimide-Tr?ger's base for the selective sensing of chemical explosives in competitive aqueous media

The 4-amino-1,8-naphthalimide-Tr?ger's base fluorophore, TBNap-TPy, adorned with phenyl-terpyridine moiety was synthesised and assessed for its aggregation-induced emission (AIE) behaviour. TBNap-TPy was further employed as a fluorescent sensor for the di

A novel bis(terpyridine) with π?conjugated phenyl viologen and its metallo- supramolecular polymers: Synthesis and electrochromism

A novel phenylene viologen functionalized bis(terpyridine) is synthesized and characterized with 1HNMR and Maldi-tof-MS. This rod-like and π-conjugated molecule, 1,1'-[4'-(4-phenyl)-2,2:6′,2″- terpyridine-4,4′-bipyridine-1,1′-diium dichloride (

Self-assembly and photo-responsive behavior of bis-terpyridyl Eu3+-complex L1

In the present paper, a bis-terpyridyl Eu3+ complex (bis-terpyridyl Eu3+-complex L1) was synthesized through the coordination between Eu3+ and a compound L1 with an azobenzene-functionalized chain between the two terpyridi