17831-07-1

Basic information

• Product Name: cis-1-trichloromethyl-2-bromocyclohexane
• CAS NO: 17831-07-1
• Molecular Weight: 280.419
• Mol File: 17831-07-1.mol

Chemical Properties

• CAS DataBase Reference: cis-1-trichloromethyl-2-bromocyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1-trichloromethyl-2-bromocyclohexane(17831-07-1)
• EPA Substance Registry System: cis-1-trichloromethyl-2-bromocyclohexane(17831-07-1)

Safety Data

• Hazardous Substances Data: 17831-07-1(Hazardous Substances Data)

Upstream product

• 75-62-7 Bromotrichloromethane 
• 110-83-8 cyclohexene 

Relevant articles and documents

Addition of bromotrichloromethane and tetrachloromethane to cis-cyclooctene, cyclohexene, and norbornadiene in the presence of palladium(II) complexes

Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.

ADDITION OF POLYHALOGENO DERIVATIVES TO OLEFINS IN THE PRESENCE OF DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II) AND PROPYLAMAGNESIUM BROMIDE

Bromotrichloromethane and carbon tetrachloride add to monosubstituted and 2,2- and 1,2-disubstituted and trisubstituted olefins in the presence of the products from the reaction of nickel(II) complexes and alkylmagnesium halides.The trichloromethyl group is attached to the least substituted carbon atom of the double bond.