178425-56-4

Basic information

• Product Name: Benzene, (1,2,2-tribromocyclopropyl)-
• CAS NO: 178425-56-4
• Molecular Formula: C9H7Br3
• Molecular Weight: 354.867
• Mol File: 178425-56-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, (1,2,2-tribromocyclopropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1,2,2-tribromocyclopropyl)-(178425-56-4)
• EPA Substance Registry System: Benzene, (1,2,2-tribromocyclopropyl)-(178425-56-4)

Safety Data

• Hazardous Substances Data: 178425-56-4(Hazardous Substances Data)

Upstream product

• 75-25-2 Bromoform 
• 98-81-7 1-bromovinylbenzene 
• 558-13-4 carbon tetrabromide 
• 98-83-9 isopropenylbenzene 
• 98-86-2 acetophenone 

Downstream Products

• 6142-95-6 phenylpropargyl aldehyde diethyl acetal 
• 53868-46-5 α-phenyl-β-ethoxyacrolein 
• 87406-33-5 1-phenyl-propynone-diethylacetal 
• 912922-63-5 1,2-dibromo-4,5-diphenylbenzene 
• 1191231-10-3 1,2-dibromo-4,5-diphenylcyclohexa-1,4-diene 
• 1314716-39-6 diphenyl(2-phenylcycloprop-1-enyl)methanol 
• 1314716-58-9 4-hydroxy-2-phenyloct-1-en-3-one 
• 1314716-57-8 4-hydroxy-2,6-diphenylhex-1-en-3-one 
• 1314716-56-7 1-hydroxy-1,3-diphenylbut-3-en-2-one 
• 1314716-54-5 4-hydroxy-4-methyl-2-phenylpent-1-en-3-one 
• 1314716-55-6 1-hydroxy-1,1,3-triphenylbut-3-en-2-one 

Relevant articles and documents

Synthesis of functionalized cyclopropylboronic esters based on a 1,2-metallate rearrangement of cyclopropenylboronate

A procedure converting tribromocyclopropane to densely functionalized β-selenocyclopropylboronic ester using the 1,2-metallate rearrangement of a boron ate-complex has been developed. Treatment of an in situ-generated cyclopropenylboronic ester ate-complex with phenylselenenyl chloride triggered stereospecific rearrangement to produce functionalized cyclopropanes. DFT calculations for 1,2-metallate rearrangement suggested that the reaction proceeds through a seleniranium intermediate. This journal is

Regioselective carbon-carbon bond cleavage in the oxidation of cyclopropenylcarbinols

The strained double bond of cyclopropenylcarbinols undergoes a facile oxidation reaction to lead to unsaturated carbonyl derivatives. The distribution of the formed products depends on the relative stability of carbon-centered radical species, and the Sha

gem-Dihalocyclopropane formation by iron/copper activation of tetrahalomethanes in the presence of nucleophilic olefins. Evidence for a carbene pathway

The activation of CBr4 and CCl4 by a bimetallic iron/copper couple in acetonitrile is a new, inexpensive, nontoxic and efficient procedure for gem-dibromo- and gem-dichloromethylenation of nucleophilic alkenes. This new route to gem-dihalocyclopropanes involves dihalocarbene species.