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The first asymmetric total syntheses of (+)-lycorine and (+)-1-deoxylycorine
Schultz, Arthur G.,Holoboski, Mark A.,Smyth, Mark S.
, p. 6210 - 6219 (2007/10/03)
The first asymmetric total syntheses of (+)-1-deoxylycorine (2a) and (+)-lycorine (2b), the unnatural enantiomer of lycorine (1), are described. Construction of lactam 12, a key intermediate in the synthesis of both 2a and 2b, began by Birch reduction-alk
