178482-75-2Relevant academic research and scientific papers
Manganese(I)-Catalyzed Substitutive C?H Allylation
Liu, Weiping,Richter, Sven C.,Zhang, Yujiao,Ackermann, Lutz
supporting information, p. 7747 - 7750 (2016/07/07)
The first manganese(I)-catalyzed C?H allylations with ample scope were achieved by carboxylate assistance. The highly selective C?H/C?O functionalizations proved viable with densely substituted allyl carbonates, and the organometallic C?H allylation strategy set the stage for expedient late-stage diversification with excellent levels of positional selectivity.
Titanocene-catalyzed cyclocarbonylation of o-allyl aryl ketones to γ- butyrolactones
Kablaoui, Natasha M.,Hicks, Frederick A.,Buchwald, Stephen L.
, p. 4424 - 4431 (2007/10/03)
A method for the transformation of o-allyl aryl ketones to γ- butyrolactones using a catalytic amount of Cp2Ti(PMe3)2 or Cp2Ti(CO)2 iS described. This catalytic 'hetero Pauson-Khand'-type process proc
