178674-64-1Relevant academic research and scientific papers
Ir Complexes with P4 Bicyclotetraphosphane and P8 Cunean as Ligands - CO Insertion into an Ir-P Bond
Scheer, Manfred,Becker, Uta,Matern, Eberhard
, p. 721 - 724 (1996)
The reaction of [Cp*Ir(CO)2] with white phosphorus under photochemical or thermal conditions produces the bicyclotetraphosphane complexes 1 and 2 and the cunean-type complex 3. The products were characterized by NMR, IR, and mass spectroscopy as well as by X-ray structure analyses. Complex 1 reacts with CO with insertion into a Ir-P bond to form 2 and finally [CpIr(CO)2]. VCH Verlagsgesellschaft mbH, 1996.
