Chemische Berichte p. 721 - 724 (1996)
Update date:2022-07-29
Topics:
Scheer, Manfred
Becker, Uta
Matern, Eberhard
The reaction of [Cp*Ir(CO)2] with white phosphorus under photochemical or thermal conditions produces the bicyclotetraphosphane complexes 1 and 2 and the cunean-type complex 3. The products were characterized by NMR, IR, and mass spectroscopy as well as by X-ray structure analyses. Complex 1 reacts with CO with insertion into a Ir-P bond to form 2 and finally [CpIr(CO)2]. VCH Verlagsgesellschaft mbH, 1996.
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Doi:10.1016/0040-4020(96)00267-0
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(1998)Doi:10.1039/c3pp50186h
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