17878-08-9Relevant academic research and scientific papers
Separation of optically active ethynylsilane derivatives and their polymerization by transition-metal catalysts
Kawakami, Yusuke,Omote, Masakatsu,Imae, Ichiro,Shirakawa, Eiji
, p. 7461 - 7468 (2007/10/03)
Optically pure (-)-(4-bromophenyl)ethynylmethyl(1-naphthyl)silane[(-)-1], (-)-1,2-diethynyl-1,2-dimethyl-1,2-di(1-naphthyl)disilane [(-)-2], and (+)-1,2-diethynyl-1,2-dimethyl-1,2-diphenyldisilane [(+)-3] were separated by a chromatographic technique on a
Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis
Cerveau, Geneviève,Chappellet, Sabrina,Corriu, Robert J.P.,Dabiens, Bertrand
, p. 92 - 99 (2007/10/03)
The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds, since this coupling reaction appeared compatible with the presence of Si(OR)3 groups.
