178814-03-4

Basic information

• Product Name: 3-[Methyl-(2-methylamino-phenyl)-amino]-3H-benzo[de]isochromen-1-one
• Synonyms: 3-[Methyl-(2-methylamino-phenyl)-amino]-3H-benzo[de]isochromen-1-one
• CAS NO: 178814-03-4
• Molecular Weight: 318.375
• Mol File: 178814-03-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-[Methyl-(2-methylamino-phenyl)-amino]-3H-benzo[de]isochromen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[Methyl-(2-methylamino-phenyl)-amino]-3H-benzo[de]isochromen-1-one(178814-03-4)
• EPA Substance Registry System: 3-[Methyl-(2-methylamino-phenyl)-amino]-3H-benzo[de]isochromen-1-one(178814-03-4)

Safety Data

• Hazardous Substances Data: 178814-03-4(Hazardous Substances Data)

Upstream product

• 14955-69-2 3-chloro-1H,3H-naphtho<1,8-cd>pyran-1-one 
• 3213-79-4 N,N'-dimethyl-1,2-phenylenediamine 
• 82-86-0 acenaphthene quinone 
• 30934-48-6 1,8-naphthaldehydic acid methyl ester 
• 5811-87-0 1,8-naphthalaldehydic acid 
• 178814-02-3 8-(1,3-Dimethyl-2,3-dihydro-1H-benzoimidazol-2-yl)-naphthalene-1-carboxylic acid methyl ester 

Relevant articles and documents

Formal transfers of hydride from carbon-hydrogen bonds. Attempted generation of H2 by intramolecular protonolyses of the activated carbon-hydrogen bonds of dihydrobenzimidazoles

Protonolyses of carbon-hydrogen bonds can occur under suitable conditions to produce carbocations and H2. In an effort to accelerate these fundamental reactions, we have attempted to make them intramolecular by devising compounds in which carbon-hydrogen bonds designed to be particularly good formal donors of hydride are held in close proximity to acidic sites. Dihydrobenzimidazoles 4 and 11 are compounds of this type, since the carbon-hydrogen bonds at C2 are activated as formal donors of hydride by adjacent lone pairs in a dihydroaromatic ring, and acidic anilinium and carboxylic acid groups are held nearby. Unfortunately, this proximity does not lead to the formation of H2 by protonolysis; instead, other reactions intervene when compounds 4 and 11 are subjected to pyrolysis.