17882-06-3 Usage
General Description
Trimethylsilylbenzenesulfonate is a specialized chemical compound commonly used in various scientific and industrial processes. As a sulfonate ester derivative, it inherits properties that include enhanced solubility in water and potential as a catalyst for alkylation, esterification, and condensation reactions. It is a moderately toxic compound that requires stringent handling and disposal procedures. The trimethylsilyl group in the compound often serves as a protective group in organic synthesis, as it increases compound stability, and can be readily removed when no longer needed. Despite its potential hazards, trimethylsilylbenzenesulfonate is valuable in chemical manufacturing and research due to its range of applications.
Check Digit Verification of cas no
The CAS Registry Mumber 17882-06-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,8,8 and 2 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 17882-06:
(7*1)+(6*7)+(5*8)+(4*8)+(3*2)+(2*0)+(1*6)=133
133 % 10 = 3
So 17882-06-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H14O3SSi/c1-14(2,3)12-13(10,11)9-7-5-4-6-8-9/h4-8H,1-3H3
17882-06-3Relevant articles and documents
Trimethylsilyl directed aromatic sulfonation with sulfur trioxide- dioxane complex
Wuts, Peter G. M.,Wilson, Katherin E.
, p. 1593 - 1595 (1998)
A mild procedure for trimethylsilyl group directed sulfonation through ipso aromatic substitution has been developed using in situ generated sulfur trioxide-dioxane complex. The process is effective with electron rich aromatic rings, but fails in the case of aromatic rings substituted by groups such as a carboxylate. Aromatic heterocycles form sulfur trioxide complexes which deactivate them to substitution.
α-(TRIALKYLSILYL)-, α-(TRIALKYLGERMYL)-, AND α-(TRIALKYLSTANNYL)-ALKANESULFONIC ESTERS AND AMIDES AND TRIMETHYLSILYL SULFONATES: THEIR SYNTHESIS AND SOME OF THEIR REACTIONS
Shipov, A. G.,Baukov, Yu. I.
, p. 1642 - 1657 (2007/10/02)
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Bis Sulfate as an Organosilicon Synthon
Voronkov, M. G.,Roman, V. K.,Maletina, E. A.
, p. 277 - 280 (2007/10/02)
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