178939-03-2

Upstream product

• 141247-15-6 (2E,6E)-(4R,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-octa-2,6-dienedioic acid diethyl ester 
• 98-88-4 benzoyl chloride 
• 178939-01-0 (E)-(4R,5R,6R,7R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6,7-dihydroxy-oct-2-enedioic acid diethyl ester 
• 143104-88-5 diethyl 4,5-dihydroxy-2,6-octadienedioate 
• 114473-50-6 (4R,5R)-{5-[(E)-2''-ethoxycarbonyl-vinyl]-2',2'-dimethyl-[1',3']-dioxolan-4-yl}-(E)-acrylic acid ethyl ester 

Downstream Products

• 178939-05-4 (E)-(4R,5R,6R,7R)-4,7-Bis-benzoyloxy-5-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-oct-2-enedioic acid diethyl ester 
• 178939-06-5 (E)-(4S,5R,6R,7R)-4,7-Bis-benzoyloxy-5-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-oct-2-enedioic acid diethyl ester 
• 178939-18-9 Benzoic acid (R)-[(4R,5S,6R)-5-(tert-butyl-dimethyl-silanyloxy)-6-((E)-2-ethoxycarbonyl-vinyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-ethoxycarbonyl-methyl ester 
• 178939-04-3 (E)-(4R,5S,6R,7R)-7-Benzoyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,6-dihydroxy-oct-2-enedioic acid diethyl ester 

Relevant academic research and scientific papers

Chemoselectivity in the manipulation of polyhydroxylated compounds derived from the diastereoselective dihydroxylation of optically active allylic enoate alcohols

An efficient, practical and stereoselective route for the preparation of several polyols and their corresponding lactols and lactones is described. They are promising precursors for the synthesis of several structurally interesting compounds.