178963-22-9

Upstream product

• 140658-12-4 2-(methylphenylphosphinyl)-α,α-bis(trifluoromethyl)phenylmethanol 
• 178879-53-3 2-{2-[(2,2-Diphenyl-2-phenylamino-ethyl)-phenyl-phosphinoyl]-phenyl}-1,1,1,3,3,3-hexafluoro-propan-2-ol 
• 574-45-8 N-(diphenylmethylidene)phenylamine 

Downstream Products

• 530-48-3 1,1-Diphenylethylene 
• 178879-56-6 Phenyl-(1-phenyl-3,3-bis-trifluoromethyl-2-oxa-1λ⁵-phospha-indan-1-ylidene)-amine 
• 3461-34-5 methyl 3,3-diphenylacrylate 
• 140658-17-9 1-Phenyl-3,3-bis-trifluoromethyl-2-oxa-1-phospha-indan 1-oxide 
• 178879-53-3 2-{2-[(2,2-Diphenyl-2-phenylamino-ethyl)-phenyl-phosphinoyl]-phenyl}-1,1,1,3,3,3-hexafluoro-propan-2-ol 
• 178879-55-5 C₃₇H₂₈F₆NO₃P 

Relevant academic research and scientific papers

Synthesis and thermolysis of pentacoordinate 1,2-azaphosphetidines

Pentacoordinate 1,2-azaphosphetidines bearing the Martin ligand were synthesized by the intramolecular dehydration of the corresponding β-amino phosphine oxides with Mitsunobu reagent (Ph3P-EtO2CN=NCO2Et). The X-ray crystallographic analysis of 1,2,4,4,-tetraphenyl derivative shows that it has a distorted trigonal bipyramidal structure with oxygen and nitrogen atoms at apical positions. Their thermolyses gave the corresponding olefins along with a cyclic iminophosphorane, which was readily hydrolyzed to give the cyclic phosphinate and aniline.

N-apicale 1,2λ5-Azaphosphetidine mit P-Pentakoordination und ihre N-aequatorialen Pseudorotamere

Keywords: 1,2λ5-Azaphosphetidine; Heterocyclen; Olefinbildung; Pseudorotamere

Synthesis, Structures, and Thermolysis of Four-Membered Heterocycles Containing a Highly Coordinate Main Group Element

The oxetanes containing highly coordinate B, Si, Ge, Sn, P, S, and Se and an azaphosphetidine were successfully synthesized. All compounds except B and Sn compounds have the Martin ligand. The X-ray crystallographic analysis indicated that they have a dis