179007-18-2

Basic information

• Product Name: [(η(5)-C5H4CONH-CH2Ph)Co(CO)2]
• CAS NO: 179007-18-2
• Molecular Weight: 313.258
• Mol File: 179007-18-2.mol

Chemical Properties

• CAS DataBase Reference: [(η(5)-C5H4CONH-CH2Ph)Co(CO)2](CAS DataBase Reference)
• NIST Chemistry Reference: [(η(5)-C5H4CONH-CH2Ph)Co(CO)2](179007-18-2)
• EPA Substance Registry System: [(η(5)-C5H4CONH-CH2Ph)Co(CO)2](179007-18-2)

Safety Data

• Hazardous Substances Data: 179007-18-2(Hazardous Substances Data)

Upstream product

• 179007-17-1 [(η(5)-C5H4COO(N-succinimidyl))Co(CO)2] 
• 100-46-9 benzylamine 

Relevant articles and documents

Synthesis, reactivity and X-ray molecular structure of the activated ester complex [( η5-C5H4COONS) Co( CO) 2] (NS = N-succinimidyl)

The title compound [(η5-C5H4COONS)Co(CO)2] (2) was prepared in high yield (91%) by treatment of the organometallic carboxylic acid [(η5-C5H4COOH)Co(CO)2] (1) with N-hydroxysuccinimide in the presence of dicyclohexylcarbodiimide. The activated ester complex 2 was identified by spectroscopic methods, in addition its X-ray structure was determined. Compound 2 crystallizes in the triclinic space group P1 with a = 6.1880(8), b = 9.722(1), c= 10.869(1) A, α = 83.37(1), β = 83.91(1) and γ = 86.30(1)°, V-645(1) A3 and Z = 2. The stability of the above species 2 and its reactivity as labelling agent for amines and amino-esters are investigated and discussed.