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1794-51-0

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1794-51-0 Usage

Description

((E)-3-CHLORO-1-METHYL-PROPENYL)-BENZENE, with the molecular formula C10H11Cl, is an organic compound characterized by a benzene ring with a chloromethyl group and a methyl-propenyl group. ((E)-3-CHLORO-1-METHYL-PROPENYL)-BENZENE is known for its reactivity due to the presence of the chloro and methyl-propenyl groups, which make it a versatile building block in various chemical processes and industries.

Uses

Used in Chemical Synthesis:
((E)-3-CHLORO-1-METHYL-PROPENYL)-BENZENE is used as an intermediate in the synthesis of pharmaceuticals and agrochemicals, contributing to the development of new and improved products in these industries.
Used in Polymer and Resin Production:
((E)-3-CHLORO-1-METHYL-PROPENYL)-BENZENE is utilized in the production of polymers and resins, which are essential materials in various applications, including coatings, adhesives, and plastics.
Used in Chemical Processes:
Due to its reactivity, ((E)-3-CHLORO-1-METHYL-PROPENYL)-BENZENE is employed in various chemical processes, where it can be further transformed into other valuable chemical products.

Check Digit Verification of cas no

The CAS Registry Mumber 1794-51-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,7,9 and 4 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1794-51:
(6*1)+(5*7)+(4*9)+(3*4)+(2*5)+(1*1)=100
100 % 10 = 0
So 1794-51-0 is a valid CAS Registry Number.

1794-51-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-chlorobut-3-en-2-ylbenzene

1.2 Other means of identification

Product number -
Other names 1-Chlor-3-phenyl-but-2-en

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1794-51-0 SDS

1794-51-0Relevant articles and documents

The role of ion-molecule pairs in solvolysis reactions. Nucleophilic addition of water to a tertiary allylic carbocation

Jia, Zhi Sheng,Ottosson, Henrik,Zeng, Xiaofeng,Thibblin, Alf

, p. 182 - 187 (2007/10/03)

The acid-catalyzed solvolysis of 2-methoxy-2-phenyl-3-butene (1-OMe) in 9.09 vol % acetonitrile in water provides 2-hydroxy-2-phenyl-3-butene (1-OH) as the predominant product under kinetic control along with the rearranged alcohol 1-hydroxy-3-phenyl-2-butene (2-OH) and a small amount of the rearranged ether 2-OMe. The more stable isomer 2-OH is the predominant product after long reaction time, Keq = [2-OH]eq/[1-OH]eq = 16. The ether 2-OMe reacts to give 2-OH and a trace of 1-OH. Solvolysis of 1-OMe in 18O-labeled water/acetonitrile shows complete incorporation of 18O in the product 1-OH, confirming that the reaction involves cleavage of the carbon-oxygen bond to the allylic carbon. A completely solvent-equilibrated allylic carbocation is not formed since the solvolysis of the corresponding chloride 1-chloro-3-phenyl-2-butene (2-C1) yields a larger fraction of 1-OH. This may be attributed to a shielding effect from the chloride leaving group. Quantum chemical calculations of the geometry and charge distribution show that the cation should rather be described as a vinyl-substituted benzyl cation than as an allyl cation, which is in accord with its higher reactivity at the tertiary carbon.

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