1795-20-6Relevant academic research and scientific papers
From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides
Perez Garcia, Pablo M.,Di Franco, Thomas,Epenoy, Alexandre,Scopelliti, Rosario,Hu, Xile
, p. 258 - 261 (2016/01/12)
Replacement of a dimethyl amino group of the amidobis(amine) nickel(II) pincer complex (1), [(MeN2N)Ni-Cl], by a pyrrolidino group resulted in a new nickel(II) pincer complex (2), [(PyrNMeNN)Ni-Cl]. Complex 2 is an efficient catalyst for Kumada and Suzuki-Miyaura cross-coupling of nonactivated secondary alkyl halides, while complex 1 is largely inactive. The significant activity difference is tentatively attributed to a minimal structural difference, which leads to a more hemilabile ligand.
Thermal Addition of Alkanes to Alkenes. V. Addition of Cyclohexane to 1-Octene in a Free Radical Chain reaction at Supercritical Fluid Conditions
Metzger, Juergen O.
, p. 767 - 781 (2007/10/02)
Alkanes can be added to alkenes in a thermally initiated free radical chain reaction ("ane reaction").Kinetic and mechanistic studies on the addition of cyclohexane (1) to 1-octene (2) (molar ratio = 100:1) at 330-450 deg C and pressures of up to 300 bar
