179555-12-5

Basic information

• Product Name: 3-Pyridinecarboxylic acid, 6-amino-4-methyl-, methyl ester
• CAS NO: 179555-12-5
• Molecular Formula: C8H10N2O2
• Molecular Weight: 166.18
• Mol File: 179555-12-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Pyridinecarboxylic acid, 6-amino-4-methyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pyridinecarboxylic acid, 6-amino-4-methyl-, methyl ester(179555-12-5)
• EPA Substance Registry System: 3-Pyridinecarboxylic acid, 6-amino-4-methyl-, methyl ester(179555-12-5)

Safety Data

• Hazardous Substances Data: 179555-12-5(Hazardous Substances Data)

Upstream product

• 98198-48-2 2-amino-5-bromo-4-methylpyridine 

Downstream Products

• 1312556-65-2 7-methylimidazo[1,2-a]pyridine-6-carboxylic acid 
• 1224465-02-4 5-methoxycarbonyl-4-methyl-2-hydroxypyridine 
• 179555-15-8 2-amino-5-hydroxymethyl-4-methylpyridine 

Relevant articles and documents

Synthesis of a series of iridium complexes bearing substituted 2-pyridonates and their catalytic performance for acceptorless dehydrogenation of alcohols under neutral conditions

A series of Cp*Ir complexes bearing 5- and 4,5-substituted 2-pyridonate ligands have been synthesized and their catalytic performance for acceptorless dehydrogenation of alcohols has been investigated under neutral conditions. Electron-withdrawing groups such as methoxycarbonyl, trifluoromethyl, cyano, and nitro groups at the 5-position promoted the acceptorless dehydrogenation of 1-phenylethanol, whereas electron-donating methyl group at the 5-position retarded the reaction. Furthermore, introduction of methyl group at the 4-position improved the catalytic performance. Thus, Cp*Ir(5-trifluoromethyl-4-methyl-2-pyridonate)Cl (2bc) exhibited the highest catalytic performance among the complexes examined, and also showed good catalytic performance for acceptorless dehydrogenation of primary alcohols.