179927-31-2Relevant academic research and scientific papers
Exploratory experiments with aryl telluride carbohydrates. Synthesis of carbocycles using intramolecular radical cyclization
Barton, Derek H.R.,Gero, Stephane D.,Holliday, Pascale,Quiclet-Sire, Beatrice
, p. 8233 - 8244 (2007/10/03)
The preparation of cyclohexanoids and cyclopentanoids, potential precursors of biologically interesting molecules is described. The key step of the synthesis is an exo cyclization of 5-hexenyl or 6-heptenyl radicals. The radical, generated by radical exchange from carbohydrate anisyl tellurides (D-galactose or D-arabinose) cyclized into polyhydroxylated cyclohexane or cyclopentane derivatives.
