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Usage

Uses

Used in Chemical Synthesis:
C₃₀H₃₅Cl₂N₂PRuSCH₂Cl₂ is used as a reagent in chemical synthesis for its potential to facilitate the formation of new compounds through its unique combination of elements.
Used in Catalysis:
In the field of catalysis, C₃₀H₃₅Cl₂N₂PRuSCH₂Cl₂ is used as a catalyst to enhance the rate of chemical reactions, taking advantage of its organometallic properties.
Used in Material Science:
C₃₀H₃₅Cl₂N₂PRuSCH₂Cl₂ is used as a component in material science to develop new materials with specific properties, such as improved conductivity or stability.
Used in Research:
In the academic and research community, C₃₀H₃₅Cl₂N₂PRuSCH₂Cl₂ is used as a research tool in organometallic chemistry to study the interactions and reactions of complex metal-organic compounds.

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 75-09-2 dichloromethane 

Relevant academic research and scientific papers

Air-Stable NNS (ENENES) Ligands and Their Well-Defined Ruthenium and Iridium Complexes for Molecular Catalysis

We introduce ENENES, a new family of air-stable and low-cost NNS ligands bearing NH functionalities of the general formula E(CH2)mNH(CH2)nSR, where E is selected from -NC4H8O, -NC4H8, or -N(CH3)2, m and n = 2 and/or 3, and R = Ph, Bn, Me, or SR (part of a thiophenyl fragment). The preparation and characterization of more than 15 examples of well-defined Ru and Ir complexes supported by these ligands that are relevant to bifunctional metal-ligand M/NH molecular catalysis are reported. Reactions of NNS ligands with suitable Ru or Ir precursors afford rich and diverse solid-state and solution chemistries, producing monometallic molecules as well as bimetallics in which the ligand coordinates to the metal via either bidentate (κ2[N,N'] or κ2[N',S]) or tridentate (κ3[N,N',S]) binding modes, depending on the basicity of the sulfur atom, CH2 chain length (m or n parameter), or identity of the transition metal. In the case of Ir, ligands bearing benzyl substituents lead to unprecedented κ4[N,N',S,C]-tetradentate core-structure complexes of the type [IrIIIHCl{κ4(N,N',S,C)-ligand}], resulting from ortho-metalation via C-H oxidative addition. Fourteen of these Ru and Ir complexes have been crystallographically characterized. Air- and moisture-stable complexes of the type trans-[RuIICl2{κ3[N,N',S]-ligand}(L)] (L = PPh3, PCy3, DMSO), and others, effect the selective hydrogenation of methyl trifluoroacetate into the important synthon trifluoroacetaldehyde methyl hemiacetal in basic methanol under relatively mild conditions (35-40 °C, 25 bar H2) with reasonable turnover numbers (i.e., > 1000), whereas the air-stable Ir monohydride complexes [IrIIIHCl{κ4(N,N',S,C)-ligand}] exhibit excellent catalytic activities and high chemoselectivity for the same reaction, reaching turnover numbers of >10 000.