180056-70-6

Basic information

• Product Name: 5-[(E)-3-(4-Nitro-phenyl)-allyloxy]-1-phenyl-1H-tetrazole
• Synonyms: 5-[(E)-3-(4-Nitro-phenyl)-allyloxy]-1-phenyl-1H-tetrazole
• CAS NO: 180056-70-6
• Molecular Weight: 323.311
• Mol File: 180056-70-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-[(E)-3-(4-Nitro-phenyl)-allyloxy]-1-phenyl-1H-tetrazole(CAS DataBase Reference)
• NIST Chemistry Reference: 5-[(E)-3-(4-Nitro-phenyl)-allyloxy]-1-phenyl-1H-tetrazole(180056-70-6)
• EPA Substance Registry System: 5-[(E)-3-(4-Nitro-phenyl)-allyloxy]-1-phenyl-1H-tetrazole(180056-70-6)

Safety Data

• Hazardous Substances Data: 180056-70-6(Hazardous Substances Data)

Upstream product

• 882-06-4 4-nitro-trans-cinnamic acid 
• 140-10-3 (E)-3-phenylacrylic acid 
• 24393-61-1 ethyl (E)-3-(4-nitrophenyl)-2-propenoate 
• 14210-25-4 5-Chloro-1-phenyltetrazole 
• 35271-56-8 (E)-4-nitrocinnamyl alcohol 

Relevant articles and documents

A kinetic investigation of the thermal rearrangement of allyloxytetrazoles to N-allyltetrazolones

The mechanism of the thermal rearrangement of 1-aryl-5-allyloxytetrazoles 1 to give 1-aryl-4-allyltetrazolones 2 in very high yield has been investigated through kinetic studies in one polar and one less polar solvent. The results suggest mainly a concerted [3,3] sigmatropic process, in which a partially positively charged allyl group migrates from oxygen to nitrogen, similar to the polar transition state found in the Claisen rearrangement.