35271-56-8

Basic information

• Product Name: 4-nitrocinnamyl alcohol
• Synonyms: 4-NITROCINNAMYL ALCOHOL
• CAS NO: 35271-56-8
• Molecular Formula: C₉H₉NO₃
• Molecular Weight: 179.17
• Mol File: 35271-56-8.mol
• Article Data: 62

Chemical Properties

• Melting Point: 127 °C
• Boiling Point: 325.3±22.0 °C(Predicted)
• Appearance: /
• Density: 1.282±0.06 g/cm3(Predicted)
• Solubility: Chloroform, Dichloromethane, Ethyl Acetate
• PKA: 13.91±0.10(Predicted)
• CAS DataBase Reference: 4-nitrocinnamyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-nitrocinnamyl alcohol(35271-56-8)
• EPA Substance Registry System: 4-nitrocinnamyl alcohol(35271-56-8)

Safety Data

• Hazardous Substances Data: 35271-56-8(Hazardous Substances Data)

Upstream product

• 61266-32-8 3-(4-nitrophenyl)prop-2-yn-1-ol 
• 636-98-6 p-nitrobenzene iodide 
• 41234-97-3 2,2-dibutyl-2,5-dihydro-1,2-oxastannole 
• 953-26-4 ethyl 4-nitrocinnamate 
• 619-89-6 p-nitrocinnamic acid 
• 123232-63-3 1-(4-nitrophenyl)-prop-2-en-1-ol 
• 49678-08-2 3-(4-nitrophenyl)-propenal 
• 555-16-8 4-nitrobenzaldehdye 
• 140-10-3 (E)-3-phenylacrylic acid 
• 882-06-4 4-nitro-trans-cinnamic acid 
• 637-57-0 p-nitrocinnamic acid methyl ester 
• 637-57-0 methyl 4-nitrocinnamate 
• 71269-07-3 3-(4-nitrophenyl)-2-propenyl chloride 
• 24393-61-1 ethyl (E)-3-(4-nitrophenyl)-2-propenoate 

Downstream Products

• 99361-40-7 p-Nitro-cinnamyl-thiocyanat 
• 1507-90-0 p-nitrocinnamyl chloride 
• 75059-04-0 1-(p-nitrophenyl)-3-bromopropene-1 
• 1885-06-9 [(2R,3S)-3-(4-Nitro-phenyl)-oxiranyl]-methanol 
• 143058-48-4 [(2S,3R)-3-(4-Nitro-phenyl)-oxiranyl]-methanol 
• 1734-79-8 3-(4-nitrophenyl)-2-propenal 
• 92963-45-6 p-Nitro-cinnamyl-p-tolyl-ether 
• 92963-43-4 4-Methyl-2-<1-(p-nitrophenyl)-1-propenyl>-phenol 
• 1147334-98-2 C₉H₅N₃O₅ 
• 1147334-72-2 3-(hydroxymethyl)-4-(4-nitrophenyl)-1,2,5-oxadiazole-2-oxide 
• 1335232-86-4 1S,2S-1-(4-nitrophenyl)glycerol 
• 1335232-84-2 (2R,3R)-3-hydroxy-para-nitrophenylalaninol 
• 1346693-55-7 2,2,2-trichloro-N-(1-(4-nitrophenyl)allyl)acetamide 
• 80793-24-4 3-(4-nitrophenyl)propanal 

Relevant articles and documents

Oxoammonium-Mediated Allylsilane–Ether Coupling Reaction

A new C(sp3)?H functionalization reaction consisting of the oxidative α-allylation of allyl- and benzyl- methyl ethers has been developed. The C?C coupling could be carried out under mild conditions thanks to the use of cheap and green oxoammonium salts. The scope of the reaction was studied over 27 examples, considering the nature of the substituents on the two coupling partners.

Stereodivergent Nucleophilic Additions to Racemic β-Oxo Acid Derivatives: Fast Addition Outcompetes Stereoconvergence in the Archetypal Configurationally Unstable Electrophile

Additions of carbon nucleophiles to racemic α-stereogenic β-oxo acid derivatives that deliver enantiomerically enriched tertiary alcohols are valuable, but uncommon. This article describes stereodivergent Cu-catalyzed borylative cyclizations of racemic β-oxo acid derivatives bearing tethered pro-nucleophilic olefins to deliver highly functionalized cyclopentanols containing four contiguous stereogenic centers. The reported protocol is applicable to a range of β-oxo acid derivatives, and the diastereomeric products are readily isolable by typical chromatographic techniques. α-Stereogenic-β-keto esters are typically thought to have extreme or spontaneous configurational fragility, but mechanistic studies for this system reveal an unusual scenario wherein productive catalysis occurs on the same time scale as background substrate racemization and completely outcompetes on-cycle epimerization, even under the basic conditions of the reaction.

Asymmetric Synthesis of Functionalized 9-Methyldecalins Using a Diphenylprolinol-Silyl-Ether-Mediated Domino Michael/Aldol Reaction

Substituted 9-methyldecalin derivatives containing an all carbon quaternary chiral center were synthesized with excellent enantioselectivity via an organocatalyst-mediated domino reaction. The first reaction is a diphenylprolinol silyl ether-mediated Michael reaction, and the second reaction is an intramolecular aldol reaction. The enantiomerically pure catalyst is involved in both reactions.