1801-37-2Relevant academic research and scientific papers
Chemical transformations of solvent-derived ozonolysis products: Improved synthesis of polycyclic 1,2,4,6-tetroxepanes from α-alkoxy α′-hydroperoxy cyclic ethers and aldehydes
McCullough, Kevin J.,Ushigoe, Yoshihiro,Tanaka, Shogo,Masuyama, Araki,Nojima, Masatomo
, p. 3053 - 3057 (2007/10/03)
α-Alkoxy α′-hydroperoxy cyclic ethers condense with aliphatic aldehydes under acidic conditions to produce the bicyclic 1,2,4,6-tetroxepanes. By X-ray crystallographic analysis, the tetroxepanes 5b and 12b, derived from cyclocondensation of the hydroperoxides 4 and 8 respectively with acetaldehyde, were shown to be exo-isomers.
Ozonolyses of 1,2-Diphenyl- and 2-Phenylindene
Sugimoto, Toshiya,Teshima, Koichi,Nakamura, Norinaga,Nojima, Masatomo,Kusabayashi, Shigekazu,McCullough, Kevin J.
, p. 135 - 141 (2007/10/02)
Ozonolyses of 1,2-diphenylindene (7), 2-phenylindene (18), and the structurally related acyclic keto olefins 13, 14, 26, and 32 were conducted in MeOH/CH2Cl2 at -70 and 0 deg C.The structure of the indenes, 7 and 18, and the rection temperature, were foun
Ozonolysis of a Series of 1-Substituted Indenes. The Substituent Steric Effects on Ozonide Exo/Endo Ratios
Miura, Masahiro,Nojima, Masatomo,Kusabayashi, Shigekazu,McCullough, Kevin J.
, p. 2932 - 2936 (2007/10/02)
The ozonolysis of a series of disubstituted (1,2 and 1,3) and trisubstituted (1,2,3) indenes 1-28 in carbon tetrachloride at 20 deg C has been investigated.The major product in each case was the corresponding bicyclic ozonide, usually obtained as a mixtur
