180153-84-8

Upstream product

• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 156768-68-2 (2S,3S)-2,3-O-(4-methoxybenzylidene)-1,2,3,4-butanetetraol 
• 130874-90-7 4,5-dimethyl (4R,5R)-2-(4-methoxyphenyl)-1,3-dioxolane-4,5-dicarboxylate 

Downstream Products

• 180153-88-2 (S)-3-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-ethyl]-1-trimethylsilanyl-hexa-1,5-diyn-3-ol 
• 180153-86-0 (S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-1-trimethylsilanyl-pent-1-yn-3-one 

Relevant academic research and scientific papers

Efficient synthesis of a carbocyclic core moiety with the stereochemistry of the C-1027 chromophore

A stereoselective and concise route to the bicyclo[7.3.0]dodecadiyne core moiety (26) of the C-1027 chromophore (1) through highly efficient LiN(TMS)2/CeCl3-mediated cyclization of alkynyl aldehyde 24 has been established.