180195-00-0Relevant academic research and scientific papers
Sigmatropic-[2,3]-wittig rearrangement of α-allylic-heterosubstituted methylphosphonates. Rearrangement in the sulfur series
Makomo, Hubert,Masson, Serge,Putman, Didier,Saquet, Monique,Simeon, Fabrice,About-Jaudet, Elie,Collignon, Noel
, p. 193 - 202 (1996)
The diisopropyl (allylthiomethyl)phosphonates (variously substituted on the allylic group) are submitted to the [2,3]-sigmatropic rearrangement, via either the carbanions or the sulfonium ylides. Synthetic potentialities are examined, and in particular ne
