Sigmatropic-[2,3]-wittig rearrangement of α-allylic-heterosubstituted methylphosphonates. Rearrangement in the sulfur series

Article abstract of DOI:10.1080/10426509608046363

The diisopropyl (allylthiomethyl)phosphonates (variously substituted on the allylic group) are submitted to the [2,3]-sigmatropic rearrangement, via either the carbanions or the sulfonium ylides. Synthetic potentialities are examined, and in particular ne

Full text of DOI:10.1080/10426509608046363

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Phosphorus, Sulfur, and Silicon and the
Related Elements
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SIGMATROPIC-[2,3]-WITTIG
REARRANGEMENT OF α-
ALLYLIC-HETEROSUBSTITUTED
METHYLPHOSPHONATES.
REARRANGEMENT IN THE SULFUR SERIES
Hubert Makomo a , Serge Masson a , Didier Putman a , Monique
Saquet a , Fabrice Simeon a , Elie About-jaudet b & Noël Collignon b
a Laboratoire de Chimie Moléculaire et Thio-organique, URA CNRS
480, Université de Caen et ISMRA , 6 Bd Mal Juin, 14050, Caen,
France
b Laboratoire d'Hétérochimie Organique, INSA-IRCOF , Place E.
Blondel, BP 08, 76131, Mont-Saint-Aignan, Cedex, France
Published online: 04 Oct 2006.
To cite this article: Hubert Makomo , Serge Masson , Didier Putman , Monique Saquet , Fabrice
Simeon , Elie About-jaudet & Noël Collignon (1996) SIGMATROPIC-[2,3]-WITTIG REARRANGEMENT
OF α-ALLYLIC-HETEROSUBSTITUTED METHYLPHOSPHONATES. REARRANGEMENT IN THE SULFUR
SERIES, Phosphorus, Sulfur, and Silicon and the Related Elements, 112:1-4, 193-202, DOI:
10.1080/10426509608046363
To link to this article: http://dx.doi.org/10.1080/10426509608046363
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