18028-00-7Relevant academic research and scientific papers
Concerning the mechanism of the reductive cleavage of α-nitrocumene and cumyl chloride
Denney, Donald B.,Denney, Dorothy Z.,Fenelli, Steven P.
, p. 5397 - 5402 (1997)
The reductive cleavages of α-nitrocumene and cumyl chloride by sodium naphthalenide in tetrahydrofuran have been studied. It is concluded that the cumyl carbanion is the first intermediate formed in these reactions.
Friedel-Crafts acetylation and benzoylation of benzylsilanes and xanthenes
Georgakilas, Vasilios,Perdikomatis, Gerasimos P.,Triantafyllou, Anastasios S.,Siskos, Michael G.,Zarkadis, Antonios K.
, p. 2441 - 2447 (2007/10/03)
The synthesis of p-acetyl and p-benzoyl derivatives of various benzylsilanes (p-R1CO-C6H4-CR2R3- SiMe3: R1, R2, R3=Me, H, H; Me, H, Ph; Me, H, Me; Me, Me, M
ORGANOMETALLIC COMPOUNDS IN ORGANIC SYNTHESIS-PART 17; REACTIONS OF TRICARBONYLCYCLOHEXADIENYLIRON SALTS WITH O-SILYLATED ENOLATES, ALLYL SILANES AND ASPECTS OF THEIR SYNTHETIC EQUIVALENTS
Birch, Arthur J.,Kelly, Lawrence F.,Narula, Acharan S.
, p. 1813 - 1824 (2007/10/02)
Efficient C-C bond formation results during reactions of O-silylated enolates and allyltrialkylsilanes with a range of tricarbonylcyclohexadienyliron salts to give tricarbonylcyclohexadieneiron complexes in good to excellent yields.This represents a new a
