18036-64-1Relevant academic research and scientific papers
Cobalt(II) Chloride Catalysed Regioselective Cleavage of Oxiranes with Chlorotrimethylsilane
Iqbal, Javed,Khan, Mohd. Amin
, p. 1157 - 1158 (1988)
Oxiranes can be cleaved regioselectively with chlorotrimethylsilane in presence of cobalt(II) chloride to the corresponding O-silylated vicinal chlorohydrins in excellent yields.
Catalysis mechanisms in the reaction of chlorotrimethylsilane with 1-phenoxy-2,3-epoxypropane
Popov,Anikeev,Kostenko,Koblik
, p. 258 - 262 (2007/10/03)
The efficient catalysis with tetraethylammonium chloride and pyridine in the reaction between chlorotrimethylsilane and 1-phenoxy-2,3-epoxypropane occurs along two independent pathways: of basic and of nucleophilic character. The quantitative evaluation o
REGIOSELECTIVITY, KINETICS, AND MECHANISM OF THE ADDITION OF TRIMETHYLCHLOROSILANE TO 1-PHENOXY-2,3-EPOXYPROPANE
Popov, A. F.,Anikeev, A. V.,Kostenko, L. I.,Koblik, I. V.
, p. 413 - 417 (2007/10/02)
The reaction of trimethylchlorosilane with 1-phenoxy-2,3-epoxypropane takes place through the silylation of 1-phenoxy-3-chloro-2-propanol. The regioselectivity of the process is determined by the regioselectivity of hydrochlorination of the α-oxide, while the rate is determined by the concentration of its corresponding α-chlorohydrin.
SODIUM BROMIDE CATALYSED REGIOSELECTIVE CLEAVAGE OF OXIRANES WITH CHLOROTRIMETHYLSILANE
Iqbal, Javed,Khan, M. Amin,Ahmad, Saeed
, p. 641 - 644 (2007/10/02)
Sodium bromide efficiently catalyses the regioselective cleavage of oxiranes with chlorotrimethylsilane to the corresponding O-silyiated chlorohydrins in excellent yield.
NUCLEOPHILIC CATALYSIS IN THE INSERTION OF SILICON HALIDES INTO OXIRANES: A SYNTHESIS OF O-PROTECTED VICINAL HALOHYDRINS
Andrews, Glenn, C.,Crawford, Thomas C.,Contillo, Leonard G.
, p. 3803 - 3806 (2007/10/02)
Silicon halides in the presence of nucleophilic catalysts react with epoxides to form O-protected vicinal halohydrins with enhanched regioselectivity.
