180401-30-3

Basic information

• Product Name: Li(C₄H₈O)4⁽¹⁺⁾*Ni((CH₃)3C₆H₂)3^(1-)=[Li(C₄H₈O)4][Ni((CH₃)3C₆H₂)3]
• CAS NO: 180401-30-3
• Molecular Weight: 711.618
• Mol File: 180401-30-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Li(C₄H₈O)4⁽¹⁺⁾*Ni((CH₃)3C₆H₂)3^(1-)=[Li(C₄H₈O)4][Ni((CH₃)3C₆H₂)3](CAS DataBase Reference)
• NIST Chemistry Reference: Li(C₄H₈O)4⁽¹⁺⁾*Ni((CH₃)3C₆H₂)3^(1-)=[Li(C₄H₈O)4][Ni((CH₃)3C₆H₂)3](180401-30-3)
• EPA Substance Registry System: Li(C₄H₈O)4⁽¹⁺⁾*Ni((CH₃)3C₆H₂)3^(1-)=[Li(C₄H₈O)4][Ni((CH₃)3C₆H₂)3](180401-30-3)

Safety Data

• Hazardous Substances Data: 180401-30-3(Hazardous Substances Data)

Upstream product

• 29046-78-4 (1,2-dimethoxyethane)dichloronickel(II) 

Relevant articles and documents

Synthesis and X-ray crystal structure of [Li(C4H8O)4][Ni(2,4,6-Me3C 6H2)3]

The tetrahydrofuran-solvated lithium salt of the ato anion [Ni(mes)3]- (mes = mesityl, 2,4,6-Me3C6H2) was obtained as a crystalline solid from the interaction of NiCl2(dme), (dme = 2,2′-dimethoxyethane) and mesityl lithium in Et2O-C4H8O. The blue compound 1 is unstable above ca - 10°C and the X-ray crystal structure was determined at low temperature. The metal centre was found to exhibit an unusual T-shaped coordination geometry, which can be explained in terms of CH3 ... Ni agostic interactions at the fourth site of a formally square-planar NiII centre. Reactions of 1 with donor ligands produced Ni(2,6-Me2C6H3NC)4, Ni(Ph2PCH2CH2PPh2)2 and Ni(mes)2(Me2NCH2CH2NMe2). Crown copyright