Synthesis and X-ray crystal structure of [Li(C4H8O)4][Ni(2,4,6-Me3C 6H2)3]

DOI: 10.1016/0277-5387(96)00056-3

Source and publish data:

Polyhedron p. 3163 - 3166 (1996)

Update date:2022-08-04

Topics:

Authors:

Hay-Motherwell, Robyn

Wilkinson, Geoffrey

Sweet, Tracy K. N.

Hursthouse, Michael B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0277-5387(96)00056-3

The tetrahydrofuran-solvated lithium salt of the ato anion [Ni(mes)₃]^- (mes = mesityl, 2,4,6-Me₃C₆H₂) was obtained as a crystalline solid from the interaction of NiCl₂(dme), (dme = 2,2′-dimethoxyethane) and mesityl lithium in Et₂O-C₄H₈O. The blue compound 1 is unstable above ca - 10°C and the X-ray crystal structure was determined at low temperature. The metal centre was found to exhibit an unusual T-shaped coordination geometry, which can be explained in terms of CH₃ ... Ni agostic interactions at the fourth site of a formally square-planar Ni^II centre. Reactions of 1 with donor ligands produced Ni(2,6-Me₂C₆H₃NC)₄, Ni(Ph₂PCH₂CH₂PPh₂)₂ and Ni(mes)₂(Me₂NCH₂CH₂NMe₂). Crown copyright

Full text of DOI:10.1016/0277-5387(96)00056-3

Products guided by the article

Product name:Li(C₄H₈O)4⁽¹⁺⁾*Ni((CH₃)3C₆H₂)3^(1-)=[Li(C₄H₈O)4][Ni((CH₃)3C₆H₂)3]

Cas No:180401-30-3

R&D Labs maybe for 180401-30-3

Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing

Relevant to this article

Studies on histaminergic compounds VIII. A new series of compounds showing H₁-antagonistic and H₂-agonistic properties; synthesis, in vitro pharmacology and structure-activity relationships

Doi:10.1016/0223-5234(87)90288-1
(1987)
A binuclear Cu^II metallacycle capable of discerning between pyrazine and its different methyl-substituted derivatives based on reversible intracage metal-ligand binding

Doi:10.1002/chem.200802690
(2009)
1-Bromo-2-(diphenylphosphinoyl)ethyne and 1-bromo-2-(p-tolylsulfinyl)ethyne: versatile reagents eventually leading to benzocyclotrimers

Doi:10.1016/j.tetlet.2009.02.064
(2009)
DIASTEREOSELECTIVE SPIROANNELATION

Doi:10.1016/S0040-4039(00)96679-6
(1987)
Coordination chemistry of [HFe(CN)₂(CO)₃]^- and its derivatives: Toward a model for the iron subsite of the [NiFe]-hydrogenases

Doi:10.1021/ic900200s
(2009)
Doi:10.1021/ja01604a060
(1956)

Article Doi