180468-85-3Relevant academic research and scientific papers
Novel Halogen Exchange Reactions between Halosilanes and Rh(I) or Ir(I) Complexes
Yamashita, Hiroshi,Kobayashi, Toshi-aki,Hayashi, Teruyuki,Tanaka, Masato
, p. 471 - 474 (2007/10/02)
Vaska-type complexes such as MCl(CO)L2 (M=Rh or Ir, L= tertiary phosphine) or the Wilkinson complex RhCl(PPh3)3 underwent halogen exchange reactions with halosilanes Me3SiX (X=Br, I) to give MX(CO)L2 or RhX(PPh3)3 respectively with the formation of Me3SiC
