36713-95-8 Usage
Uses
Used in Chemical Catalysis:
Rhodium, carbonylchlorobis(trimethylphosphine)is used as a catalyst for various chemical reactions such as hydrogenation, hydroformylation, and carbonylation. Its ability to selectively activate and transform specific bonds in organic molecules makes it a valuable tool in the synthesis of complex organic compounds.
Used in Pharmaceutical Synthesis:
In the pharmaceutical industry, Rhodium, carbonylchlorobis(trimethylphosphine)is utilized as a catalyst for the synthesis of various pharmaceuticals. Its selectivity and reactivity contribute to the production of high-quality and efficient drug compounds.
Used in Agrochemical Production:
Rhodium, carbonylchlorobis(trimethylphosphine)is also employed in the agrochemical sector for the synthesis of pesticides and other agrochemical products. Its catalytic properties aid in the creation of effective and targeted agrochemicals.
Used in Fine Chemicals Synthesis:
This coordination complex is used as a catalyst in the synthesis of fine chemicals, which are high-purity chemicals used in various industries, including fragrances, flavors, and specialty chemicals.
Used in Specialty Materials and Polymers Production:
Rhodium, carbonylchlorobis(trimethylphosphine)is utilized in the production of specialty materials and polymers, where its catalytic properties are essential for creating specific polymer structures and materials with unique properties.
Check Digit Verification of cas no
The CAS Registry Mumber 36713-95-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,7,1 and 3 respectively; the second part has 2 digits, 9 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 36713-95:
(7*3)+(6*6)+(5*7)+(4*1)+(3*3)+(2*9)+(1*5)=128
128 % 10 = 8
So 36713-95-8 is a valid CAS Registry Number.
36713-95-8Relevant academic research and scientific papers
Cis-Hydrlooacylrhodlum
Milatein, David
, p. 1549 - 1551 (2008/10/08)
Stable cis -hydridoacylrinodium compleses.
Synthesis of η1 Oxygen-Bound Rhodium Enolates. Applications to Catalytic Aldol Chemistry
Slough, Greg A.,Bergman, Robert G.,Heathcock, Clayton H.
, p. 938 - 949 (2007/10/02)
Oxygen-bound rhodium enolate complexes are prepared by metathesis of carbonylbis(phosphine)rhodium(I) halides and potassium enolates, 3-6.Rhodium enolates of acetophenone (7), propiophenone (9), ethyl mesityl ketone (10), and ethyl tert-butyl ketone (11) were prepared and fully characterized.Complex 11 condenses with benzaldehyde under a variety of conditions to produce isolable rhodium aldolate complex 12.Cleavage of 12 with trimethylsilyl chloride yields aldol silyl ether and rhodium chloride.Similar treatment of 12 with an enol silane affords the aldol silylether and a rhodium enolate.A catalytic aldol reaction involving enol silanes, silylketene acetals, and benzaldehyde under rhodium catalysis is presented.Deuterium, phosphorus, and carbon NMR were used to demonstrate the intermediacy of rhodium enolates and aldolates in the aldol process and to elucidate the gross mechanistic features of the catalytic cycle.
