18055-66-8Relevant articles and documents
Si-N Heterodehydrocoupling with a Lanthanide Compound
Cibuzar, Michael P.,Waterman, Rory
supporting information, p. 4395 - 4401 (2019/01/03)
[La{N(SiMe3)2}3THF2] (1) is an effective precatalyst for the heterodehydrocoupling of silanes and amines. Coupling of primary and secondary amines with aryl silanes was achieved with a loading of 0.8 mol % of [L
Tris(oxazolinyl)boratomagnesium-catalyzed cross-dehydrocoupling of organosilanes with amines, hydrazine, and ammonia
Dunne, James F.,Neal, Steven R.,Engelkemier, Joshua,Ellern, Arkady,Sadow, Aaron D.
, p. 16782 - 16785 (2011/12/04)
We report magnesium-catalyzed cross-dehydrocoupling of Si-H and N-H bonds to give Si-N bonds and H2. A number of silazanes are accessible using this method, as well as silylamines from NH3 and silylhydrazines from N2H4. Kinetic studies of the overall catalytic cycle and a stoichiometric Si-N bond-forming reaction suggest nucleophilic attack by a magnesium amide as the turnover-limiting step.
