180679-60-1Relevant academic research and scientific papers
1,3-elimination in 2-(tert-alkyl)adamantan-2-ols: An easy synthesis of bridgehead-substituted 2,4-dehydroadamantanes
Lomas, John S.
, p. 588 - 591 (1996)
When 2-(tert-alkyl)adamantan-2-ols (where the substituent is bi- or tricyclic) are thermolysed or the corresponding bromide is refluxed in pyridine, an unusual 1,3-elimination occurs, leading to 2,4-dehydroadamantanes bearing the tert-alkyl substituent on the cyclopropane system.
