Journal of Physical Organic Chemistry p. 588 - 591 (1996)
Update date:2022-08-04
Topics:
Lomas, John S.
When 2-(tert-alkyl)adamantan-2-ols (where the substituent is bi- or tricyclic) are thermolysed or the corresponding bromide is refluxed in pyridine, an unusual 1,3-elimination occurs, leading to 2,4-dehydroadamantanes bearing the tert-alkyl substituent on the cyclopropane system.
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