1,3-elimination in 2-(tert-alkyl)adamantan-2-ols: An easy synthesis of bridgehead-substituted 2,4-dehydroadamantanes

DOI: 10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

Source and publish data:

Journal of Physical Organic Chemistry p. 588 - 591 (1996)

Update date:2022-08-04

Topics:: Authors:

Lomas, John S.

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Article abstract of DOI:10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

When 2-(tert-alkyl)adamantan-2-ols (where the substituent is bi- or tricyclic) are thermolysed or the corresponding bromide is refluxed in pyridine, an unusual 1,3-elimination occurs, leading to 2,4-dehydroadamantanes bearing the tert-alkyl substituent on the cyclopropane system.

Full text of DOI:10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

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Article Doi

1,3-elimination in 2-(tert-alkyl)adamantan-2-ols: An easy synthesis of bridgehead-substituted 2,4-dehydroadamantanes

DOI: 10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

Source and publish data:

Authors:

Article abstract of DOI:10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

Full text of DOI:10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

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