1,3-elimination in 2-(tert-alkyl)adamantan-2-ols: An easy synthesis of bridgehead-substituted 2,4-dehydroadamantanes

DOI: 10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

Source and publish data:

Journal of Physical Organic Chemistry p. 588 - 591 (1996)

Update date:2022-08-04

Topics:: Authors:

Lomas, John S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

When 2-(tert-alkyl)adamantan-2-ols (where the substituent is bi- or tricyclic) are thermolysed or the corresponding bromide is refluxed in pyridine, an unusual 1,3-elimination occurs, leading to 2,4-dehydroadamantanes bearing the tert-alkyl substituent on the cyclopropane system.

Full text of DOI:10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

Products guided by the article

Product name:2-(1-bicyclo[2.2.2]octyl)adamantan-2-ol

Cas No:180679-60-1

R&D Labs maybe for 180679-60-1

Shanghai Hohance Chemical Co., ltd

Contact:13914753421

Address:Fl.5；Bld. 70, Lane 1500; Xinfei Road
Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Weifang Adde Economic And Trade Co.,LTD.

Contact:86-536-8885548

Address:Room 1402,Wanda Plaza B Block,No.958,Yuanfei Road,Kuiwen District
Joyochem Co., Ltd.

website:https://sdjingyuan.lookchem.com/

Contact:86-531-82687998

Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China

Relevant to this article

Stereoselective synthesis of (-)-ara-cyclohexenyl-adenine

Doi:10.1016/j.tetlet.2007.03.031
(2007)
Doi:10.1016/S0040-4039(01)86956-2
(1973)
Unusual fluorescence of: O-phenylazonaphthol derivatives with aggregation-induced emission and their use in two-photon cell imaging

Doi:10.1039/c9cc03106e
(2019)
Doi:10.1002/hlca.19540370208
(1954)
A kinetic separation method for the stereoselective preparation of (Z)- and (E)-monofluoroenynes from E/Z mixtures of 1-bromo-1-fluoroolefins

Doi:10.1016/S0022-1139(01)00529-2
(2001)
Doi:10.1002/hlca.19420250625
(1942)

Article Doi

1,3-elimination in 2-(tert-alkyl)adamantan-2-ols: An easy synthesis of bridgehead-substituted 2,4-dehydroadamantanes

DOI: 10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

Source and publish data:

Authors:

Article abstract of DOI:10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

Full text of DOI:10.1002/(SICI)1099-1395(199608)9:8<588::AID-POC824>3.0.CO;2-V

Products guided by the article

R&D Labs maybe for 180679-60-1

Relevant to this article

Hot Product