180889-65-0Relevant academic research and scientific papers
Stereoselective synthesis of the bicyclic core structure of the highly oxidised sesquiterpene neoliacinic acid
Clark, J. Stephen,Dossetter, Alexander G.,Whittingham, William G.
, p. 5605 - 5608 (2007/10/03)
The bicyclic core (3) of the sesquiterpene neoliacinic acid (1) has been constructed in a stereoselective manner by [2,3]-sigmatropic ring-expansion of an oxonium ylide generated catalytically from the α-diazo ketone 4.
