180889-64-9

Upstream product

• 147193-45-1 1-[(3-bromopropoxy)methyl]-4-methoxybenzene 
• 15186-48-8 2,3-isopropylidene-glyceraldehyde 

Downstream Products

• 180889-57-0 (S)-3-Allyloxy-1-diazo-6-(4-methoxy-benzyloxy)-hexan-2-one 
• 180889-62-7 Acetic acid (2S,3S,5S)-2-[3-(4-methoxy-benzyloxy)-propyl]-3-methyl-5-vinyl-tetrahydro-furan-3-yl ester 
• 180889-60-5 (2S,5S)-2-[3-(4-Methoxy-benzyloxy)-propyl]-5-vinyl-dihydro-furan-3-one 
• 180889-65-0 (S)-2-Allyloxy-5-(4-methoxy-benzyloxy)-pentanoic acid 
• 180889-66-1 (2S,3S,5S)-2-[3-(4-Methoxy-benzyloxy)-propyl]-3-methyl-5-vinyl-tetrahydro-furan-3-ol 
• 180889-59-2 (S)-2-Allyloxy-5-(4-methoxy-benzyloxy)-pentanal 
• 180889-58-1 (R)-4-[(S)-1-Allyloxy-4-(4-methoxy-benzyloxy)-butyl]-2,2-dimethyl-[1,3]dioxolane 

Relevant academic research and scientific papers

Stereoselective synthesis of the bicyclic core structure of the highly oxidised sesquiterpene neoliacinic acid

The bicyclic core (3) of the sesquiterpene neoliacinic acid (1) has been constructed in a stereoselective manner by [2,3]-sigmatropic ring-expansion of an oxonium ylide generated catalytically from the α-diazo ketone 4.

Synthesis of the functionalised core of neoliacinic acid

An advanced intermediate in the synthesis of neoliacinic acid has been prepared, and the structure and relative stereochemistry have been confirmed by X-ray crystallography.