180912-63-4

Upstream product

• 2043-61-0 cyclohexanecarbaldehyde 
• 180912-43-0 Cyclohexyl-(2,3-dimethoxy-6-methoxymethoxy-phenyl)-methanol 
• 180912-45-2 2-Cyclohexylmethyl-3,4-dimethoxy-1-methoxymethoxy-benzene 
• 180912-59-8 2,3-Dichloro-5-cyclohexylmethyl-6-methoxy-[1,4]benzoquinone 
• 180912-50-9 Cyclohexyl-(2-methoxy-6-methoxymethoxy-phenyl)-methanol 
• 180912-52-1 2-Cyclohexylmethyl-1-methoxy-3-methoxymethoxy-benzene 
• 180912-56-5 2-(cyclohexylmethyl)-3-methoxycyclohexa-2,5-diene-1,4-dione 
• 180912-54-3 2-Cyclohexylmethyl-3-methoxy-phenol 
• 133129-56-3 1,2-dimethoxy-4-(methoxymethoxy)benzene 
• 57234-28-3 1-methoxy-3-(methoxymethoxy)benzene 
• 180912-48-5 2-cyclohexylmethyl-3,4-dimethoxyphenol 
• 946528-69-4 3-(cyclohexylmethyl)-5-(3'-cyclohexylmethyl-2'-hydroxy-4',5'-dimethoxyphenyl)-2-methoxy-[1,4]benzoquinone 
• 180912-61-2 2-Chloro-5-cyclohexylmethyl-3-(3-cyclohexylmethyl-2-hydroxy-4,5-dimethoxy-phenyl)-6-methoxy-[1,4]benzoquinone 

Downstream Products

• 180912-65-6 2,6-Bis-cyclohexylmethyl-3,7-dihydroxy-8-methoxy-dibenzofuran-1,4-dione 

Relevant academic research and scientific papers

A novel construction of dibenzofuran-1,4-diones by oxidative cyclization of quinone-arenols

A novel oxidative cyclization of quinone-arenols 5 leading to products 6 with a dibenzofuran-1,4-dione structure, which forms the core of several natural products, has been developed and applied to the synthesis of violet-quinone (4).

Synthesis of various model compounds for the central tricyclic ring system of popolophuanone E

An efficient synthesis of various model compounds 4a-e for the tricyclic core of popolophuanone E (1), a novel marine natural product, was accomplished; the method features highly regioselective annulation of the phenols 5a-e with the 2,3-dichloro-1,4-benzoquinones 7, 7c-e. Preliminary studies definitely demonstrated the feasibility of our designed synthetic strategy for 1 (the phenolic subunit I + the quinone subunit II → 1).