181271-17-0Relevant articles and documents
Palladium-Catalyzed 3-Aryl-5-acyl-1,2,4-thiadiazole Formation from Ketones, Amidines, and Sulfur Powder
Wang, Zilong,Xie, Hao,Xiao, Fuhong,Guo, Yanjun,Huang, Huawen,Deng, Guo-Jun
, p. 1604 - 1607 (2017)
An efficient strategy for the preparation of 3,5-disubstituted 1,2,4-thiadiazoles from ketones, amidines, and sulfur powder under palladium-catalyzed conditions was developed. In this transformation, aromatic ketones act as both the carbon and acyl source
Synthesis of 6aλ4-thia-1,2,4,6-tetraazapentalenes
L'abbe, Gerrit,Vossen, Peggy,Dehaen, Wim,Meervelt, Luc Van
, p. 335 - 338 (2007/10/03)
The title compounds were synthesized by two approaches, starting either from a 1,2,4-thiadiazole or a 1,2.3-thiadiazole derivative, and were shown by X-ray analysis of a selected example 9 to have two S-N bonds around 1.9 Angstroem.