18135-48-3

Basic information

• Product Name: 3-Iodo-1-(trimethylsilyl)propane
• Synonyms: 3-Iodo-1-(trimethylsilyl)propane;(3-Iodopropyl)trimethylsilane
• CAS NO: 18135-48-3
• Molecular Formula: C₆H₁₅ISi
• Molecular Weight: 242.17
• Mol File: 18135-48-3.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Iodo-1-(trimethylsilyl)propane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Iodo-1-(trimethylsilyl)propane(18135-48-3)
• EPA Substance Registry System: 3-Iodo-1-(trimethylsilyl)propane(18135-48-3)

Safety Data

• Hazardous Substances Data: 18135-48-3(Hazardous Substances Data)

Upstream product

• 2344-83-4 (3-chloropropyl)trimethylsilane 
• 54597-87-4 3-(trimethylsilyl)-1-propanol, methanesulfonate 
• 16494-36-3 2-iodo-5-methylthiophene 
• 762-72-1 allyl-trimethyl-silane 
• 2917-47-7 3-trimethylsilyl-1-propanol 
• 88729-78-6 3-(trimethylsilyl)propan-1-ol tosylate 

Downstream Products

• 18083-11-9 triethyl-(3-trimethylsilanyl-propyl)-ammonium; iodide 
• 88729-70-8 2-Benzyl-5-trimethylsilanyl-pentanoic acid 
• 344443-42-1 2-Phenyl-5-trimethylsilanyl-pentanoyl chloride 
• 344438-02-4 2-Benzyl-5-trimethylsilanyl-pentanoyl chloride 
• 344438-03-5 2-Phenylsulfanyl-5-trimethylsilanyl-pentanoyl chloride 
• 154673-59-3 dimethyl-(4-iodobutyl)-phenylsilane 
• 635299-19-3 (CH₃)3SiC₃H₆N(C₃H₆NCHC₆H₄OH)2 
• 17337-20-1 <5-Oxo-5-phenyl-pentyl>-trimethyl-silan 

Relevant articles and documents

Synthesis and characterization of alkylsilane ethers with oligo(ethylene oxide) substituents for safe electrolytes in lithium-ion batteries

Alkylsilane ethers, containing one or three carbon spacer groups between the silicon atom and oligo(ethylene oxide) moiety, were designed and synthesized. These compounds are non-hydrolyzable and less flammable than their alkoxysilane counterparts. A full cell test using them as electrolyte solvents showed good cycling performance in lithium-ion batteries.

Exploratory studies of H-atom abstraction and silyl-transfer photoreactions of silylalkyl ketones and (silylalkyl)phthalimides

Exploratory studies have been conducted to probe competitive H-atom abstraction and SET-promoted, silyl-transfer reactions of excited states of silylalkyl ketones and (silylalkyl)phthalimides. Photochemical investigations with the (silylalkyl)phthalimides have demonstrated that typical γ-H atom abstraction reactions occur upon irradiation in less polar and less silophilic solvents. In contrast, irradiation of these substances in polar-protic-silophilic solvents results in product formation via pathways involving SET-induced desilylation. Photoreactions of silylamido-aryl ketones in either nonsilophilic or silophilic solvents take place almost exclusively by sequential SET silyl-transfer routes to produce azetidine products. Finally, the chemical selectivities of photochemical reactions of silylpropyl-aryl ketones appear to depend on medium polarity and silophilicity. Irradiation of these substrates in less polar-nonsilophilic solvents leads to almost exclusive formation of acetophenone and vinyltrimethylsilane in essentially equal yields by a reaction pathway initiated by γ-H atom abstraction and 1,4-biradical fragmentation. However, irradiation of these substances in polar-silophilic solvents produces acetophenone and vinyltrimethylsilane in an ca. 1.7:1 ratio reflecting the fact that a silyl-transfer pathway competes with H-atom abstraction under these conditions.

N-derivatives of 1-deoxy nojirimycin

This invention relates to novel N-derivatives of 1-deoxy nojirimycin, to the method for their preparation and to their use in the treatment of diabetes and the use against retro-viruses, particularly in the treatment of acquired immuno-deficiency syndrome