2917-47-7

Basic information

• Product Name: 3-(TRIMETHYLSILYL)-1-PROPANOL
• Synonyms: 3-(TRIMETHYLSILYL)-1-PROPANOL;3-(TRIMETHYLSILYL)PROPANOL;3-(trimethylsilyl)-1-propano;1-Propanol,3-(trimethylsilyl)-;3-(TRIMETHYLSILYL)PROPANOL 97%;3-(Trimethylsilyl)-1-propanol,97%;3-(TriMethylsilyl)-1-propanol, 97% 5GR;3-trimethylsilylpropan-1-ol
• CAS NO: 2917-47-7
• Molecular Formula: C₆H₁₆OSi
• Molecular Weight: 132.28
• Product Categories: Alcohols;C2 to C6;Oxygen Compounds
• Mol File: 2917-47-7.mol
• Article Data: 9

Chemical Properties

• Melting Point: <0°C
• Boiling Point: 111-112 °C96 mm Hg(lit.)
• Flash Point: 127 °F
• Appearance: Clear colorless/Liquid
• Density: 0.832 g/mL at 25 °C(lit.)
• Vapor Pressure: 2.45mmHg at 25°C
• Refractive Index: n20/D 1.428(lit.)
• Storage Temp.: Flammables area
• CAS DataBase Reference: 3-(TRIMETHYLSILYL)-1-PROPANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(TRIMETHYLSILYL)-1-PROPANOL(2917-47-7)
• EPA Substance Registry System: 3-(TRIMETHYLSILYL)-1-PROPANOL(2917-47-7)

Safety Data

• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 16-26-36/37/39
• RIDADR: UN 1987 3/PG 3
• WGK Germany: 3
• TSCA: No
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 2917-47-7(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

3-(Trimethylsilyl)-1-propanol has been used in:the synthesis of telechelic oligomers via atom transfer radical polymerization (ATRP) of styrenethe preparation of the β-seleno-γ-silyl alcohols

InChI:InChI=1/C6H16OSi/c1-8(2,3)6-4-5-7/h7H,4-6H2,1-3H3

Upstream product

• 75-21-8 oxirane 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 18546-69-5 2,2,10,10-tetramethyl-6-(3-trimethylsilanyl-propyl)-2,10-disila-6-bora-undecane 
• 5272-36-6 3-trimethylsilyl-2-propyn-1-ol 
• 762-72-1 allyl-trimethyl-silane 
• 17887-32-0 2,2,7,7-tetramethyl-3-oxa-2,7-disila-octane 
• 75-77-4 chloro-trimethyl-silane 
• 68236-10-2 3-chloromagnesiumpropan-1-olate magnesium chloride 
• 5290-24-4 (3-acetoxy-propyl)-dichloro-methyl-silane 
• 676-58-4 methylmagnesium chloride 
• 857223-87-1 8,8-dimethyl-4-oxa-8-sila-nonanenitrile 
• 5683-30-7 3-trimethylsilylpropionic acid 
• 13617-12-4 bis(3-chloropropoxy)dimethylsilane 
• 18171-15-8 (3-chloropropoxy)trimethylsilane 

Downstream Products

• 18388-41-5 (3-Acetoxy-propyl)-trimethyl-silan 
• 937784-68-4 [3-(2-methoxy-4-nitrophenoxy)propyl]trimethylsilane 
• 3124-35-4 Trimethyl-(3-carbamoyloxy-propyl)-silan 
• 10545-34-3 3-(trimethylsilyl)propyl bromide 
• 18166-09-1 [3-(1-tert-butoxy-ethoxy)-propyl]-trimethyl-silane 
• 1616978-45-0 2-(pentafluorophenyl)-3,4-bis(3-trimethylsilylpropoxy)-5-trimethylsilylthiophene 
• 2345-40-6 4-trimethylsilanyl-butyric acid 
• 1310373-13-7 C₂₄H₃₄N₂O₄SSi 
• 1310352-91-0 C₁₇H₂₆O₃Si 
• 1029557-22-9 {3-[2-(difluoromethyl)-5-methyl-4-nitrophenoxy]propyl}(trimethyl)silane 
• 937784-72-0 5-nitro-2-[3-(trimethylsilyl)propoxy]benzaldehyde 
• 193970-87-5 C₂₀H₁₅F₁₀N₃O₃SSi 

Relevant articles and documents

Synthesis of 1-silabicyclo[4.4.0]dec-5-en-4-ones: A model of the A and B rings of 10-silatestosterone

1-Silabicyclo[4.4.0]dec-5-en-4-ones, a novel type of organosilicon compound, have been prepared from 2-methylidene-1-(3-oxopropyl)-1- silacyclohexanes by an ene reaction as the key transformation. Various routes to the starting aldehydes from 3-halopropyl, allyl, or 3-(4-methoxybenzyloxy) propylsilanes have been investigated. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

REGIO- AND STEREOSELECTIVE SYNTHESIS OF ALLYLTRIMETHYLSILANES VIA KRIEF-REICH ELIMINATION IN β-SELENO-γ-SILYL ALCOHOLS

The synthesis of (E)-allyltrimethylsilanes by regio- and stereocontrolled pathways is described based on the preference for Krief-Reich elimination over silicon-controlled rearrangement in β-seleno-γ-silyl alcohols, readily available from α-selenoaldehydes, 10 - 12.Usefulness of this protocol for the introduction of the allylsilane function α to the carbonyl group in cycloalkanones as well as for the preparation of unsymmetrically substituted allylsilanes is also reported.

Organoborane-Catalyzed Hydroalumination of Olefins

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