18138-88-0Relevant academic research and scientific papers
Alkenylation of thiophenes and furans at the 2-position and a synthesis of allenes conjugated with α,β-unsaturated ester with magnesium alkylidene carbenoids
Mori, Natsuki,Obuchi, Kazumi,Katae, Takashi,Sakurada, Jo,Satoh, Tsuyoshi
experimental part, p. 3509 - 3517 (2009/08/15)
The reaction of 1-chlorovinyl p-tolyl sulfoxides, derived from ketones and chloromethyl p-tolyl sulfoxide, with i-PrMgCl at -78 °C gave magnesium alkylidene carbenoids. Treatment of the magnesium carbenoids with 2-lithiothiophenes and 2-lithiofurans resul
A facile method for the construction of highly substituted acetonitriles and olefins. Malononitriles as acetonitrile carbanion and alkylidene dianion equivalents
Tsai, Ting-Yueh,Shia, Kak-Shan,Liu, Hsing-Jang
, p. 97 - 101 (2007/10/03)
The use of malononitrile to facilitate the preparation of highly substituted nitriles, via reductive alkylation/addition, and olefins, via a combination of reductive addition and reductive elimination, is described.
