18162-96-4Relevant academic research and scientific papers
Raman and infrared studies supported by ab initio calculations for the determination of conformational stability, silyl rotational barrier and structural parameters of cyclohexyl silane
Zheng, Chao,Subramaniam, Swaminathan,Kalasinsky, Victor F.,Durig, James R.
, p. 143 - 159 (2006)
The Raman spectra (4000-100 cm-1) of liquid and solid and infrared spectra (4000-400 cm-1) of gaseous, liquid and solid cyclohexyl silane, c-C6H11SiH3, have been recorded and assigned. These spectral
Synthesis of hydrosilanes: Via Lewis-base-catalysed reduction of alkoxy silanes with NaBH4
Aoyagi, Keiya,Ohmori, Yu,Inomata, Koya,Matsumoto, Kazuhiro,Shimada, Shigeru,Sato, Kazuhiko,Nakajima, Yumiko
supporting information, p. 5859 - 5862 (2019/05/27)
Hydrosilanes were synthesized by reduction of alkoxy silanes with BH3 in the presence of hexamethylphosphoric triamide (HMPA) as a Lewis-base catalyst. The reaction was also achieved using an inexpensive and easily handled hydride source NaBH4, which reacted with EtBr as a sacrificial reagent to form BH3in situ.
