181635-58-5

Upstream product

• 100-52-7 benzaldehyde 
• 181635-61-0 3-Methyl-2-oxo-5-(triphenyl-λ⁵-phosphanylidene)-2,5-dihydro-pyrrole-1-carboxylic acid tert-butyl ester 
• 181635-59-6 tert-butyl 5-bromo-3-methyl-2-oxo-2,5-dihydro-1H-pyrrole-1-carboxylate 
• 171017-20-2 tert-butyl 3-methyl-2-oxo-2,5-dihydro-1H-pyrrole-1-carboxylate 
• 171201-55-1 N-(tert-butoxycarbonyl)-2-(tert-butyldimethylsiloxy)-3-methyl-pyrrole 
• 181635-57-4 3-Methyl-2-oxo-5-[1-phenyl-meth-(E)-ylidene]-2,5-dihydro-pyrrole-1-carboxylic acid tert-butyl ester 
• 181635-62-1 (1-tert-butoxycarbonyl-3-methyl-3-pyrrolin)-5-yl-phosphonic acid diethyl ester 

Relevant academic research and scientific papers

Stereoselective preparation of (5E)- and (5Z)-5-benzylidene-3-methyl-3-pyrrolin-2-ones. Application to the synthesis of ampullicine and isoampullicine

The application of N-Boc-5-phosphoranylidene- and N-Boc-5-diethylphosphonate-3-methyl-3-pyrrolin-2-ones to the stereoselective synthesis of (5E)- and (5Z)-3-methyl-5-benzylidene-3-pyrrolin-2-ones is examined. The stereoselective synthesis of the growth regulators Ampullicin and Isoampullicin by using both Wittig intermediates has also been achieved.