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18166-36-4

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18166-36-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 18166-36-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,1,6 and 6 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 18166-36:
(7*1)+(6*8)+(5*1)+(4*6)+(3*6)+(2*3)+(1*6)=114
114 % 10 = 4
So 18166-36-4 is a valid CAS Registry Number.

18166-36-4Downstream Products

18166-36-4Relevant articles and documents

CATALYSIS OF HYDROSILYLATION. VII. CATALYSIS OF HYDROSILYLATION OF C=C BONDS BY RUTHENIUM PHOSPHINE COMPLEXES

Marciniec, Bogdan,Gulinski, Jacek

, p. 349 - 362 (1983)

A full account of the catalysis of hydrosilylation of the C=C bond in olefins, their derivatives with functional groups as well as in vinyl-trisubstituted silanes by ruthenium(II) and ruthenium(III) phosphine precursors is given.The ruthenium complexes are far more efficient catalysts for the hydrosilylation of 1-alkenes and vinyl-substituted silanes than for the substituted olefins and unsaturated esters.General features characterizing all hydrosilylation reactions catalyzed by the above catalysts are as follows: the reaction proceeds with alkoxy-substituted silanes(also with vinylsilanes) in the absence of solvent, and is enhanced (for RuII and olefins occurs exclusively) in the presence of molecular oxygen.Two general mechanisms are proposed for hydrosilylation of olefins and of vinylsilanes, respectively, which account for most of the experimental observations.

Catalytic Asymmetric Synthesis of Optically Active 2-Alkanols via Hydrosilylation of 1-Alkenes with a Chiral Monophosphine-Palladium Catalyst

Uozumi, Yasuhiro,Hayashi, Tamio

, p. 9887 - 9888 (2007/10/02)

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