18168-04-2Relevant academic research and scientific papers
Iron(II)-Catalyzed Hydroamination of Isocyanates
South, Amy J.,Geer, Ana M.,Taylor, Laurence J.,Sharpe, Helen R.,Lewis, William,Blake, Alexander J.,Kays, Deborah L.
, p. 4115 - 4120 (2019)
A two-coordinate Fe(II) m-terphenyl complex acts as a precatalyst for the hydroamination of isocyanates, affording urea and biuret derivatives, with product selectivity accomplished via modification of the reaction conditions. Using a more nucleophilic amine facilitates the insertion of up to four isocyanates into the N-H bond, affording triuret and tetrauret derivatives.
Developing catalytic applications of cooperative bimetallics: Competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates
Hernan-Gomez, Alberto,Bradley, Tyne D.,Kennedy, Alan R.,Livingstone, Zoe,Robertson, Stuart D.,Hevia, Eva
supporting information, p. 8659 - 8661 (2013/09/23)
Mixed-metal reagents [NaMg(CH2SiMe3)3] (1) and [(THF)NaMg(NPh2)3(THF)] [3-(THF)2] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depen
