18182-41-7Relevant academic research and scientific papers
The reaction of 1,2-disilyldisiloxane, 1-silyldisiloxane, and 1,1,1-trimethyldisiloxane with boron trichloride
Van Dyke, Charles H.,MacDiarmid, Alan G.
, p. 747 - 752 (1964)
Two new unsymmetrical disiloxanes, 1-silyldisiloxane, SiH3SiH2OSiH3, and 1,1,1-trimethyldisiloxane, (CH3)3SiOSiH3, have been synthesized and characterized. 1,2-Disilyldisiloxane, (SiH3SiH2)2O, underwent reaction with BCl3 to yield SiH3SiH2Cl. Preferential cleavage of certain silicon-oxygen bonds was observed when (CH3)3SiOSiH3, SiH3SiH2OSiH3, and also a mixture of (SiH3SiH2)2O and (SiH2)2O were treated with BCl3. The results are discussed.
