Inorganic Chemistry p. 747 - 752 (1964)
Update date:2022-08-03
Topics:
Van Dyke, Charles H.
MacDiarmid, Alan G.
Two new unsymmetrical disiloxanes, 1-silyldisiloxane, SiH3SiH2OSiH3, and 1,1,1-trimethyldisiloxane, (CH3)3SiOSiH3, have been synthesized and characterized. 1,2-Disilyldisiloxane, (SiH3SiH2)2O, underwent reaction with BCl3 to yield SiH3SiH2Cl. Preferential cleavage of certain silicon-oxygen bonds was observed when (CH3)3SiOSiH3, SiH3SiH2OSiH3, and also a mixture of (SiH3SiH2)2O and (SiH2)2O were treated with BCl3. The results are discussed.
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Doi:10.1016/0584-8539(86)80185-4
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(1991)
