18202-04-5

Basic information

• Product Name: 2-Diazocycloheptanone
• Synonyms: 2-Diazocycloheptanone
• CAS NO: 18202-04-5
• Molecular Formula: C₇H₁₀N₂O
• Molecular Weight: 0
• Mol File: 18202-04-5.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Diazocycloheptanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Diazocycloheptanone(18202-04-5)
• EPA Substance Registry System: 2-Diazocycloheptanone(18202-04-5)

Safety Data

• Hazardous Substances Data: 18202-04-5(Hazardous Substances Data)

Upstream product

• 502-42-1 cycloheptanone 
• 64799-08-2 2-formylcycloheptanone 
• 934-20-3 2-(hydroxymethylene)cycloheptanone 

Downstream Products

• 57205-01-3 2-phenylselenocyclohept-2-enone 
• 2719-26-8 N-phenylcyclohexanamide 
• 1121-66-0 2-Cyclohepten-1-one 
• 950-21-0 dispiro[5.1.5.1]tetradecane-7,14-dione 
• 3183-41-3 2-Ethylcycloheptanone 
• 99892-47-4 4,4'-Bis<1-(1-ethoxy-2-oxocycloheptyl)-3,5-dioxo-1,2,4-triazolidin-4-yl>diphenylmethan 
• 52190-41-7 2-phenylsulfanylcycloheptanone 
• 108-94-1 cyclohexanone 
• 104023-14-5 2-acetoxy-2-phenylselenocycloheptanone 
• 99892-44-1 1-(1-Ethoxy-2-oxocycloheptyl)-4-phenyl-1,2,4-triazolidin-3,5-dion 
• 4630-82-4 methyl cyclohexylcarboxylate 
• 155200-44-5 α-methoxycycloheptanone 
• 502-42-1 cycloheptanone 

Relevant articles and documents

Practical Application of the Aqueous 'Sulfonyl-Azide-Free' (SAFE) Diazo Transfer Protocol to Less α-C-H Acidic Ketones and Esters

The earlier described 'sulfonyl-Azide-free' ('SAFE') protocol for diazo transfer to CH-Acidic 1,3-dicarbonyl compounds (and their similarly activated congeners) has been extended to the less reactive monocarbonyl substrates, which previously required a se

REGIOSPECIFIC SYNTHESIS OF α-(PHENYLTHIO)CYCLOALKENONES AND OF α-PHENYL-α-(PHENYLTHIO)KETONES VIA αα-ADDITION OF PHENYLSULPHENYL CHLORIDE TO α-DIAZOKETONES

Cyclic α-diazoketones react with phenylsulphenyl chloride at room temperature to furnish α-chloro-α-(phenylthio)cycloalkanones which undergo ready dehydrochlorination to α-(phenylthio)cycloalkenones when treated with triethylamine; acyclic, terminal α-diazoketones also furnish α-chloro-α-(phenylthio)adducts which are useful electrophiles in the synthesis of α-phenyl-α-(phenylthio)ketones.