18209-60-4

Usage

Uses

Used in Organosilicon Compounds Preparation:
(N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE is used as a reagent for the preparation of organosilicon compounds, which are essential in various industries, including electronics, construction, and automotive.
Used in Surface Functionalization:
(N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE is used as a coupling agent for the functionalization of surfaces, enabling the attachment of various functional groups to surfaces, improving their properties and performance.
Used in Silicone Polymer Production:
(N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE is used in the production of silicone polymers, which are widely used in various applications, such as sealants, adhesives, and coatings, due to their excellent thermal stability, chemical resistance, and biocompatibility.
Used in Pharmaceutical and Agrochemical Synthesis:
(N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE is used as a reactive intermediate in the synthesis of pharmaceuticals and agrochemicals, contributing to the development of new drugs and pesticides with improved efficacy and safety.
Used in Chemical Research:
(N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE is used in chemical research for the study of organosilicon compounds and their applications, as well as for the development of new synthetic methods and techniques.
It is crucial to handle (N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE with caution, as it is highly reactive and can be hazardous if not properly handled and stored. Proper safety measures, such as wearing protective equipment and working in a well-ventilated area, should be taken to minimize the risks associated with its use.

InChI:InChI=1/C4H12ClNSi/c1-6(2)7(3,4)5/h1-4H3

Upstream product

• 124-40-3 dimethyl amine 
• 75-78-5 dimethylsilicon dichloride 
• 3768-58-9 bis(dimethylamino)dimethylsilane 
• 10038-98-9 germaniumtetrachloride 

Downstream Products

• 69185-21-3 p-Bromphenyl(dimethylamino)dimethylsilan 
• 22705-32-4 (dimethylamino)dimethylsilane 
• 13328-30-8 bis(N,N-dimethylamino)dichlorosilane 
• 75-78-5 dimethylsilicon dichloride 
• 136559-68-7 1-(methoxydimethylsiloxy)-6-methylcyclohexene 
• 136559-67-6 1-(methoxydimethylsiloxy)-2-methylcyclohexene 
• 181231-67-4 Dimethylaminodimethyl-n-butylsilan 
• 86071-71-8 (2-Dimethylaminophenyl)dimethylamino-dimethylsilan 
• 118319-20-3 Chloro-dimethyl-((E)-propenyl)-silane 
• 1224699-51-7 N-(2-((dimethylamino)dimethylsilyl)-1-phenylvinyl)-2,6-diisopropylbenzenamine 
• 263752-70-1 N-[(N,N-dimethylamino)dimethylsilyl]-2,6-diisopropylaniline 
• 79244-50-1 cis-SnCl₄[Si(CH₃)2[N(CH₃)2]2] 
• 16530-75-9 dimethylamidotitanium(IV) trichloride 
• 3768-58-9 bis(dimethylamino)dimethylsilane 

Relevant academic research and scientific papers

Unsymmetrically substituted dimethyldiaminosilanes as ligands towards zirconium(IV)

Unsymmetrically substituted dimethyldiaminosilanes of the general formula SiMe2(NR2) (NR′2) have been prepared by treating LiNR2 with SiMe2C1(NR′2) (NR2, NR′2 = NMe2, NC4H 8, NHiPr, NHtBu, NHCH2CH2NMe2 or NHCH2CH2-OMe). Their ligating properties towards zirconium(iv) have been investigated as a function of the nitrogen substituents and the syntheses of the binary compound Zr[SiMe2-(NiPr)(NiBu)] 2 and of the zirconium derivatives ZrX3(L) [X = Cl, NMe2; L = SiMe(NR) (NR′2), NR = NiPr, NtBu, NCH 2CH2NMe2, NCH2CH2OMe; NR′2 = NMe2, NC4H8, NHiPr, NHtBu] are also reported. The solution structures and dynamics of the compounds have been elucidated by 1D/2D multinuclear NMR spectroscopy. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

GROUP 4 METAL COMPLEX, PRODUCTION METHOD THEREOF, PREPARATION METHOD OF GROUP 4 METAL-CONTAINING THIN FILM

PROBLEM TO BE SOLVED: To provide a group 4 metal complex having excellent thermal stability and proper vapor pressure and suitable as a material for preparing a group 4 metal-containing thin film. SOLUTION: There is provided the group 4 metal complex represented by the general formula (1), where M represents a group 4 metal atom, R1, R2, R3 and R4 each represent independently a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, R5, R6 and R7 each represent independently an alkyl group having 1 to 8 carbon atoms, R8, R9 and R10 each represent independently an alkyl group having 1 to 6 carbon atoms or a di (alkyl having 1 to 3 carbon atoms) amino group. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPO&INPIT

Complexation and Exchange Reactions of some Dimethylamino-substituted Group 4 Compounds

Reactions of CH2(NMe2)2, (1), SiMe2(NMe2)2, (2), (cp=η-cyclopentadienyl), (3), and , (4), with covalent metal halides MCl4 (M=Ti,Zr,Si,Ge,or Sn) and MCl3 (M=Ti,V,or Cr) fall into two categories: (a) N-donor chelation leading to complex formation and (b) halide-NMe2 exchange.Compound (1) gives 1:1 complexes with MCl4 (M=Ti or Sn) and 2:1 complex with VCl3.Compound (2) provides 1:1 complexes with MCl4 (M=Ti,Zr,Hf, or Sn).The decomposition of TiCl4*SiMe2(NMe2)2 --> invariably occurs in both the solid state and solution.There is no reaction of (2) with metal(III) chlorides.With MCl4 (M=Si or Ge 'scrambling' reactions involving halide-NMe2 exchange occur and these have been monitored by 1H n.m.r. spectroscopy.Reactions of (3) and (4) with MCl4 (M=Si,Ge,Sn,Ti,Zr,or Hf) consistently feature halide-NMe2 exchange rather than adduct formation.All complexes have been characterised by analytical and spectroscopic (1H n.m.r. and i.r.) investigations.

Chloraminosilanes II. Preparation and spectroscopic studies on alkyl-(dimethylamino)chlorosilanes

Several new compounds containing both chloro and dimethylamino groups linked to silicon have been prepared. The general method involved reacting a solution of the appropriate polychlorosilane in ether at ca. - 50° with a chilled ethereal solution of dimethylamine. Prepared in this fashion were CH3Si(NMe2)Cl2, CH3Si(NMe2)2-Cl, PhSi(NMe2)Cl2, PhSi(NMe2)2Cl, CH3(H)Si(NMe2)Cl, (CH3)2Si(NMe2)Cl, CH2CH(CH3)Si(NMe2)Cl, and Ph2Si(NMe2)Cl. Comparison of the spectra of these compounds with those in the perhalo and peramine series showed that replacement of NMe2 for Cl resulted in an upfield shift of the resonances of the other groups linked to silicon, a shift which parallels that observed upon substitution of CH3 for Cl. The relationship of ν(SiH) in the IR and δ(SiH) in the NMR spectra was linear.