182124-65-8Relevant academic research and scientific papers
Tandem cyclization and acetalization of a homologated D-glucose delivers D-glycero-D-gulo-septanosides
Ramsubhag, Ron R.,Peczuh, Mark W.
experimental part, p. 92 - 101 (2011/07/07)
A synthesis of methyl-D-glycero-D-gulo-septanoside and allyl D-glycero-D-gulo-septanoside from a D-glucose derived heptenitol is reported. Key steps in the synthesis include the diasteroselective dihydroxylation of the heptenitol, regioselective opening o
Chemical synthesis of β-homonojirimycin, of its N-butyl derivative, and of 'methyl homoazacellobioside'
Saavedra,Martin
, p. 6987 - 6993 (2007/10/03)
β-Homonojirimycin (2) was prepared by the highly stereoselective double reductive amination of a 2,6-heptodiulose derivative (6 or 13) using ammonium formate and NaBH3CN. The process was unsuccessful with primary amines. The synthesis of N-buty
